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密闭容器中玉米淀粉/空气以及CH/玉米淀粉/空气的瞬态反应过程与机理:基于实验与模拟的定量研究

Transient reaction process and mechanism of cornstarch/air and CH/cornstarch/air in a closed container: Quantitative research based on experiments and simulations.

作者信息

Jing Qi, Wang Dan, Liu Qingming, Shen Yang, Wang Zhisong, Chen Xu, Zhong Yingpeng

机构信息

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China.

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China; Mechanical Engineering Technology Cluster TC, Campus Group T Leuven, KU Leuven, 3000 Leuven, Belgium.

出版信息

J Hazard Mater. 2021 May 5;409:124475. doi: 10.1016/j.jhazmat.2020.124475. Epub 2020 Nov 5.

Abstract

Both dust/air explosion and flammable gas/dust/air explosion are common forms of energy release. Experiments and simulation models with a multi-step chemical reaction mechanism were used to study the intensity parameters and mechanism of the CH/air explosion, cornstarch/air explosion and CH/cornstarch/air explosion in a closed container. Results showed that the peak overpressure, maximum flame temperature, and average flame propagation speed of the stoichiometric CH/air explosion reach 0.84 MPa, 2614 K and 3.5 m/s, respectively. The optimal concentration of cornstarch explosion is 750 g/m, and its peak overpressure, maximum flame temperature and average flame propagation speed are 0.76 MPa, 2098 K and 1.77 m/s, respectively. For a three-components system, adding methane can significantly increase the explosive intensity and combustion performance of cornstarch. The explosive intensity parameters (peak overpressure, maximum flame temperature, average flame propagation speed) of a certain concentration of cornstarch first increase and then decrease with the increase of methane concentration. The maximum explosion intensity parameters of a three-components system with a certain concentration of lean-methane/air are higher than that of single-phase, but always lower than that of the stoichiometric methane/air. Moreover, the mutual coordination of dust and combustible gas in energy release and the mutual competition mechanism in oxygen consumption are described.

摘要

粉尘/空气爆炸和可燃气体/粉尘/空气爆炸都是常见的能量释放形式。采用具有多步化学反应机理的实验和模拟模型,研究了密闭容器中CH/空气爆炸、玉米淀粉/空气爆炸以及CH/玉米淀粉/空气爆炸的强度参数和机理。结果表明,化学计量比的CH/空气爆炸的峰值超压、最高火焰温度和平均火焰传播速度分别达到0.84MPa、2614K和3.5m/s。玉米淀粉爆炸的最佳浓度为750g/m,其峰值超压、最高火焰温度和平均火焰传播速度分别为0.76MPa、2098K和1.77m/s。对于三元体系,添加甲烷可显著提高玉米淀粉的爆炸强度和燃烧性能。一定浓度的玉米淀粉的爆炸强度参数(峰值超压、最高火焰温度、平均火焰传播速度)随甲烷浓度的增加先增大后减小。一定浓度的贫甲烷/空气三元体系的最大爆炸强度参数高于单相体系,但始终低于化学计量比的甲烷/空气体系。此外,还描述了粉尘与可燃气体在能量释放中的相互协同作用以及在氧气消耗中的相互竞争机理。

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