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含氯化钠添加剂的超细水雾对甲烷/空气爆炸的抑制作用。

Suppression of methane/air explosion by ultrafine water mist containing sodium chloride additive.

机构信息

School of Chemical Machinery, Dalian University of Technology, No.2 Linggong Road, Ganjingzi District,Dalian, Liaoning 116024, PR China.

School of Chemical Machinery, Dalian University of Technology, No.2 Linggong Road, Ganjingzi District,Dalian, Liaoning 116024, PR China.

出版信息

J Hazard Mater. 2015 Mar 21;285:311-8. doi: 10.1016/j.jhazmat.2014.11.016. Epub 2014 Dec 2.

DOI:10.1016/j.jhazmat.2014.11.016
PMID:25528229
Abstract

The suppression effect of ultrafine mists on methane/air explosions with methane concentrations of 6.5%, 8%, 9.5%, 11%, and 13.5% were experimentally studied in a closed visual vessel. Ultrafine water/NaCl solution mist as well as pure water mist was adopted and the droplet sizes of mists were measured by phase doppler particle analyzer (PDPA). A high speed camera was used to record the flame evolution processes. In contrast to pure water mist, the flame propagation speed, the maximum explosion overpressure (ΔP(max)), and the maximum pressure rising rate ((dP/dt)max) decreased significantly, with the "tulip" flame disappearing and the flame getting brighter. The results show that the suppressing effect on methane explosion by ultrafine water/NaCl solution mist is influenced by the mist amount and methane concentration. With the increase of the mist amount, the pressure, and the flame speed both descended significantly. And when the mist amount reached 74.08 g/m(3) and 37.04 g/m(3), the flames of 6.5% and 13.5% methane explosions can be absolutely suppressed, respectively. All of results indicate that addition of NaCl can improve the suppression effect of ultrafine pure water mist on the methane explosions, and the suppression effect is considered due to the combination effect of physical and chemical inhibitions.

摘要

在一个封闭的可视容器中,实验研究了超细雾对甲烷浓度为 6.5%、8%、9.5%、11%和 13.5%的甲烷/空气爆炸的抑制作用。采用超细水/NaCl 溶液雾和纯水雾,并用相多普勒粒子分析仪(PDPA)测量雾滴尺寸。高速摄像机用于记录火焰演化过程。与纯水雾相比,火焰传播速度、最大爆炸超压(ΔP(max))和最大压力上升率((dP/dt)max)显著降低,“郁金香”火焰消失,火焰变得更亮。结果表明,超细水/NaCl 溶液雾对甲烷爆炸的抑制效果受雾量和甲烷浓度的影响。随着雾量的增加,压力和火焰速度都显著下降。当雾量达到 74.08 g/m(3)和 37.04 g/m(3)时,分别可以绝对抑制 6.5%和 13.5%甲烷爆炸的火焰。所有结果表明,添加 NaCl 可以提高超细纯水雾对甲烷爆炸的抑制效果,抑制效果被认为是物理和化学抑制的综合作用。

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