Synthesis, Structure, and Electrochemical Properties of Some Cobalt Oxalates.

Transition-metal oxalates have wide applications in magnetics, photoemission, electrochemistry, etc. Herein, using hydrothermal reactions, five cobalt(II) oxalates, NaCo(CO)·2HO (), NaCo(CO)·8HO (), KLiCo(CO) (), LiCo(CO) (), and (NH)Co(CO)F () have been synthesized, and their structures are determined from single-crystal X-ray diffraction or Rietveld refinement of powder X-ray diffraction data. Notably, and are identified for the first time. The structures of these cobalt oxalates are versatile, covering 0D, 1D, 2D, and 3D frameworks, while the coordination environments of Co centers are uniquely distorted octahedra. As representative examples, and are investigated as cathode materials for secondary batteries. Both exhibited electrochemical activity despite large cell polarization. The present study enriches the transition-metal oxalate family and provides new options for energy storage materials.