Güy Nuray, Atacan Keziban, Boutra Belgassim, Özacar Mahmut
Science & Arts Faculty, Department of Chemistry, Sakarya University, Sakarya 54050, Turkey E-mail:
Biomedical, Magnetic and Semiconductor Materials Application and Research Center (BIMAS-RC), Sakarya University, Sakarya 54050, Turkey.
Water Sci Technol. 2020 Nov;82(9):1912-1920. doi: 10.2166/wst.2020.452.
The formation of heterojunction structures of semiconductors is one of the most important techniques to increase the photocatalytic efficiency of a photocatalyst. In this paper, Ag/AgVO/TiO as a visible light response photocatalyst was prepared easily by a three step process including hydrothermal, precipitation and photoreduction. The Ag/AgVO/TiO nanocomposites demonstrated clearly increased visible light absorption and photocatalytic efficiency in degradation of Rhodamine B. The degradation yield of Rhodamine B was detected 97.3% in 45 min under visible light. Compared with AgVO, TiO and AgVO/TiO, Ag/AgVO/TiO exhibited the highest efficiency owing to synergetic effect between AgVO and TiO and surface plasmon resonance effect of Ag nanoparticles. So, the Ag/AgVO/TiO can be effectively used as an active photocatalyst under visible light and it depicts an ideal potential in elimination organic pollutants.
半导体异质结结构的形成是提高光催化剂光催化效率的最重要技术之一。本文通过水热、沉淀和光还原三步法轻松制备了Ag/AgVO/TiO可见光响应光催化剂。Ag/AgVO/TiO纳米复合材料在降解罗丹明B时表现出明显增强的可见光吸收和光催化效率。在可见光下45分钟内检测到罗丹明B的降解率为97.3%。与AgVO、TiO和AgVO/TiO相比,由于AgVO和TiO之间的协同效应以及Ag纳米颗粒的表面等离子体共振效应,Ag/AgVO/TiO表现出最高的效率。因此,Ag/AgVO/TiO可以有效地用作可见光下的活性光催化剂,并且在消除有机污染物方面展现出理想的潜力。