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CoCrFeNiTa合金在1 M氯化钠水溶液中的腐蚀行为

Corrosion Behavior of CoCrFeNiTa Alloys in 1 M Sodium Chloride Aqueous Solution.

作者信息

Tsau Chun-Huei, Hsiao Rong-Wei, Chien Tien-Yu

机构信息

Institute of Nanomaterials, Chinese Culture University, Huagang Road, 55, Shilin District, Taipei 11114, Taiwan.

出版信息

Materials (Basel). 2020 Nov 16;13(22):5157. doi: 10.3390/ma13225157.

DOI:10.3390/ma13225157
PMID:33207707
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7696295/
Abstract

This paper investigates the effects of Ta content on the microstructures, hardness and corrosion behavior of as-cast CoCrFeNiTa alloys. The results indicate that the addition of Ta can change the microstructures of these alloys to dual-phased structures (FCC + HCP), as well as increasing their hardness. This study uses constant galvanostatic/potentiometric methods to measure the polarization curves of CoCrFeNiTa, CoCrFeNiTa and CoCrFeNiTa alloys in deaerated 1 M sodium chloride solution at different temperatures. Electrochemical impedance spectroscopy is also used to analyze these alloys in sodium chloride solution. The results indicate that the CoCrFeNiTa alloy has a eutectic structure and the highest hardness. Furthermore, although the CoCrFeNiTa alloy has the best corrosion resistance, the CoCrFeNiTa alloy has the best pitting resistance among these alloys.

摘要

本文研究了Ta含量对铸态CoCrFeNiTa合金微观结构、硬度和腐蚀行为的影响。结果表明,Ta的添加可将这些合金的微观结构转变为双相结构(FCC + HCP),同时提高其硬度。本研究采用恒电流/恒电位法测量CoCrFeNiTa、CoCrFeNiTa和CoCrFeNiTa合金在不同温度下的除气1 M氯化钠溶液中的极化曲线。还使用电化学阻抗谱对这些合金在氯化钠溶液中进行分析。结果表明,CoCrFeNiTa合金具有共晶结构且硬度最高。此外,尽管CoCrFeNiTa合金具有最佳的耐腐蚀性,但CoCrFeNiTa合金在这些合金中具有最佳的耐点蚀性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/ace9032a6637/materials-13-05157-g008a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/2e33540d1978/materials-13-05157-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/28f87f76424a/materials-13-05157-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/f53555cd6ae6/materials-13-05157-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/2af0974f23ef/materials-13-05157-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/7f147fdc0bc2/materials-13-05157-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/65828061bdba/materials-13-05157-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/f8e4300f8746/materials-13-05157-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/ace9032a6637/materials-13-05157-g008a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/2e33540d1978/materials-13-05157-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/28f87f76424a/materials-13-05157-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/f53555cd6ae6/materials-13-05157-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/2af0974f23ef/materials-13-05157-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/7f147fdc0bc2/materials-13-05157-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/65828061bdba/materials-13-05157-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/f8e4300f8746/materials-13-05157-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9323/7696295/ace9032a6637/materials-13-05157-g008a.jpg

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本文引用的文献

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The Effects of Mo and Nb on the Microstructures and Properties of CrFeCoNi(Nb,Mo) Alloys.
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2
Microstructure and Corrosion Behavior of (CoCrFeNi)Nb₅ High-Entropy Alloy Coating Fabricated by Plasma Spraying.等离子喷涂制备的(CoCrFeNi)Nb₅高熵合金涂层的微观结构与腐蚀行为
Materials (Basel). 2019 Feb 27;12(5):694. doi: 10.3390/ma12050694.