Imrie C T, Paterson D A, Storey J M D, Chamignon C, Lelli M, Emsley J W, Luckhurst G R
Department of Chemistry, School of Natural and Computing Sciences, University of Aberdeen, Aberdeen AB24 3FX, United Kingdom.
Centre de RMN à Très Hauts Champs de Lyon (FRE 2034-CNRS, UCB Lyon 1, ENS Lyon), 5 rue de la Doua, 69100 Villeurbanne, France.
Phys Rev E. 2020 Oct;102(4-1):042706. doi: 10.1103/PhysRevE.102.042706.
Both ^{1}H and ^{13}C NMR spectra have been obtained in a static magnetic field of 23.5 T on a bent-shaped dimer molecule, 1^{''},7^{''}-bis(4-cyanobiphenyl-4'-yl) nonane (CB9CB), which shows the sequence of liquid crystal phases twist-bend nematic, N_{TB}, and uniaxial nematic, N_{U}, before entering the isotropic phase. The ^{1}H spectra are used to locate the temperature at which the sample melts to form a twist-bend nematic, T_{CrN_{TB}}, and then T_{N_{U}I} when the isotropic phase is entered, both in a magnetic field of 23.5 T, and to compare these with those measured at the Earth's field. The differences between these transition temperatures are found to be zero within the error in their measurement, in stark contrast to previous measurements by Salili et al. [Phys. Rev. Lett. 116, 217801 (2016)10.1103/PhysRevLett.116.217801]. In the isotropic phase in the presence of the field the sample exists in a paranematic phase in which the molecules of CB9CB are partially ordered. The ^{1}H and ^{13}C NMR spectra in the paranematic phase are used to measure the critical temperature T* below which this phase is unstable. The spectra are also used to study the structure, molecular orientational order, and distribution of molecular conformations in the paranematic phase.
在23.5 T的静磁场中,对弯曲形二聚体分子1'',7''-双(4-氰基联苯-4'-基)壬烷(CB9CB)进行了¹H和¹³C核磁共振光谱测量。该分子在进入各向同性相之前,呈现出扭曲弯曲向列相(NₜB)和单轴向列相(Nᵤ)的液晶相序列。¹H光谱用于确定样品在23.5 T磁场中熔化形成扭曲弯曲向列相的温度Tₒₙₙₜ₈,以及进入各向同性相时的温度Tₙᵤᵢ,并将这些温度与在地磁场中测量的温度进行比较。发现这些转变温度之间的差异在测量误差范围内为零,这与萨利利等人之前的测量结果[《物理评论快报》116, 217801 (2016)10.1103/PhysRevLett.116.217801]形成鲜明对比。在场存在的各向同性相中,样品处于顺磁相,其中CB9CB分子部分有序。顺磁相中的¹H和¹³C核磁共振光谱用于测量低于该相不稳定的临界温度T*。这些光谱还用于研究顺磁相中的结构、分子取向有序性和分子构象分布。