Coalbed Methane Resources and Reservoir Formation Process Key Laboratory of Ministry of Education, China University of Mining & Technology, Xuzhou, Jiangsu 221008, China.
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu University of Technology, Chengdu 610059, China.
J Nanosci Nanotechnol. 2021 Jan 1;21(1):57-71. doi: 10.1166/jnn.2021.18461.
Due to breakthroughs in the Lower Silurian Longmaxi Formation in the Sichuan Basin and multiple strata around the basin, the northern part of Guizhou adjacent to the Sichuan Basin has become a key area for shale gas exploration. Compared with the Longmaxi Formation, the Niutitang Formation displays greater TOC (total organic carbon) content, depositional thickness and distribution area, but the details remain undetermined. In the study area, the Lower Cambrian Niutitang Formation typically has high TOC content, maturity and brittle mineral content. The study area has experienced multiple periods of tectonic movement, which have great influence on the fracture and pore characteristics. The fractures are mainly structural fractures and have obvious zoning. The primary types of pores are intraparticle pores, organic matter pores, and interparticle pores. Further, macropores and mesopores less than 50 nm contribute most of the pore volume, while pores less than 2 nm contribute most of the specific surface area. Many factors affect the pore-fracture system, such as tectonism, TOC content, mineral composition, and sedimentary environment. Tectonic movements produce fractures based on the changing stress field, but the degree of fracture development does not agree well with the degree of pore development. The TOC content has good positive correlations with the development of fractures and micropores, especially for nanoporosity, while clay minerals show a negative correlation with the development of fractures but a strong positive correlation with the growth of micropores. Quartz displays a positive correlation with the development of fractures but no good correlation with pore development. Finally, the lithofacies, lithologies and mineral compositions under the control of sedimentary environments are internal factors that can impact the development of pore-fracture systems.
由于四川盆地及其周缘多个层位下志留统龙马溪组和贵州北部毗邻四川盆地地区取得了突破性进展,贵州北部毗邻四川盆地地区已成为页岩气勘探的重点区域。与龙马溪组相比,牛蹄塘组具有更大的总有机碳(TOC)含量、沉积厚度和分布面积,但细节仍不确定。在研究区,下寒武统牛蹄塘组通常具有较高的 TOC 含量、成熟度和脆性矿物含量。研究区经历了多期构造运动,对裂缝和孔隙特征有较大影响。裂缝主要为构造裂缝,具有明显的分带性。主要的孔隙类型为颗粒内孔隙、有机质孔隙和颗粒间孔隙。此外,大于 50nm 的大孔和中孔对孔体积的贡献最大,而小于 2nm 的孔对比表面积的贡献最大。许多因素影响孔隙-裂缝系统,如构造作用、TOC 含量、矿物组成和沉积环境。构造运动在变化的应力场的基础上产生裂缝,但裂缝发育程度与孔隙发育程度并不完全一致。TOC 含量与裂缝和微孔的发育呈良好的正相关,特别是对纳米孔隙,而粘土矿物与裂缝的发育呈负相关,但与微孔的生长呈强正相关。石英与裂缝的发育呈正相关,但与孔隙的发育没有很好的相关性。最后,沉积环境控制的岩相、岩性和矿物组成是影响孔隙-裂缝系统发育的内在因素。