Dujjanutat Praepilas, Muanruksa Papasanee, Kaewkannetra Pakawadee
Postdoctoral Training of Department of Biotechnology, Khon Kaen University, Khon Kaen 40002, Thailand.
Centre for Alternative Energy Research and Development (AERD), Faculty of Engineering, Khon Kaen University, Khon Kaen 40002, Thailand.
MethodsX. 2020 Nov 5;7:101128. doi: 10.1016/j.mex.2020.101128. eCollection 2020.
In this research work, analytical, experimental methods and monitoring techniques of bio-hydrogenated kerosene (BHK) production in continuous mode were presented. Two kinds of raw materials obtained from palm processing plant named as refined bleached deodorised palm oil (RPO) and palm kernel oil (PKO) were converted into BHK via hydrocracking reaction catalysed by Pd/AlO catalyst in pilot scale. Firstly, both of RPO and PKO were pretreated by thermal technique. Subsequently, fatty acid compositions of palm oils were analysed by Gas Chromatography (GC). Then, hydrocracking reaction of RPO and PKO were separately conducted in continuous high pressure packed bed reactor (HPPBR). After reaction, crude-biofuel was refined into BHK via fractional distillation. In addition, some properties of BHK obtained from RPO/PKO such as were C, H, O elements, freezing point, flash points, total acid number and carbon distribution were analysed following the ASTM and UOP 915 standards.•Thermal pretreatment of refined bleached deoderised palm oil (RPO) and palm kernel oil (PKO).•Continuous hydrocracking reaction of palm oil was conducted in pilot scale.•Characterisation of bio-hydrogenated kerosene obtained from palm oil.
在这项研究工作中,介绍了连续模式下生物氢化煤油(BHK)生产的分析方法、实验方法和监测技术。从棕榈加工厂获得的两种原料,即精炼漂白脱臭棕榈油(RPO)和棕榈仁油(PKO),在中试规模下通过钯/氧化铝催化剂催化的加氢裂化反应转化为BHK。首先,RPO和PKO均采用热技术进行预处理。随后,通过气相色谱(GC)分析棕榈油的脂肪酸组成。然后,RPO和PKO的加氢裂化反应分别在连续高压填充床反应器(HPPBR)中进行。反应后,通过分馏将粗生物燃料精炼为BHK。此外,按照ASTM和UOP 915标准分析了从RPO/PKO获得的BHK的一些性质,如碳、氢、氧元素、冰点、闪点、总酸值和碳分布。
• 精炼漂白脱臭棕榈油(RPO)和棕榈仁油(PKO)的热预处理。
• 棕榈油的连续加氢裂化反应在中试规模下进行。
• 对从棕榈油中获得的生物氢化煤油进行表征。