合成后金属化的金属有机框架作为氢甲酰化反应的原子分散催化剂
Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions.
作者信息
Tang Panjuan, Paganelli Stefano, Carraro Francesco, Blanco Matias, Riccò Raffaele, Marega Carla, Badocco Denis, Pastore Paolo, Doonan Christian J, Agnoli Stefano
机构信息
Department of Chemical Sciences and INSTM Unit, University of Padova, Via F. Marzolo 1, 35131 Padova, Italy.
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Via Torino 155, 30172 Venezia Mestre, Italy.
出版信息
ACS Appl Mater Interfaces. 2020 Dec 9;12(49):54798-54805. doi: 10.1021/acsami.0c17073. Epub 2020 Nov 24.
A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
一种具有双吡唑配体的锰基金属有机框架已用原子分散的铑和钴物种进行金属化，并用作苯乙烯氢甲酰化反应的催化剂。基于铑的材料在80°C时表现出优异的转化率，具有完全的化学选择性、对支链醛的高选择性、高可回收性以及可忽略不计的金属浸出。
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