Instituto de Grasa, Spanish National Research Council (CSIC), Ctra. de Utrera, km. 1, 41013 Seville, Spain.
School of Civil Engineering, The University of Queensland, Campus St. Lucia-AEB Ed 49, St. Lucia, QLD 4067, Australia.
Molecules. 2020 Nov 20;25(22):5438. doi: 10.3390/molecules25225438.
The olive oil production is an important industrial sector in many Mediterranean areas, but it is currently struggled by the necessity of a proper valorisation of the olive mill solid waste or alperujo. The alperujo is the main by-product generated during the two-phase olive oil extraction, accounting for up to 80% of the initial olive mass. The alperujo is a source of valuable compounds, such as the pomace olive oil or highly interesting phenolic compounds. In the present research, a novel biorefinery approach has been used for phenolic compounds recovery. However, the extraction of these valuables compounds generates different exhausted phases with high organic matter content that are required to be managed. This study consists of the evaluation of the anaerobic biodegradability of the different fractions obtained in a novel biorefinery approach for the integral valorisation of alperujo. The results show that the different phases obtained during the biorefinery of the alperujo can be effectively subjected to anaerobic digestion and no inhibition processes were detected. The highest methane yield coefficients were obtained for the phases obtained after a two-months storages, i.e., suspended solids and liquid phase free of suspended solids, which generated 366 ± 7 mL CH/g VS and 358 ± 6 mL CH/g VS, respectively. The phenol extraction process reduced the methane yield coefficient around 25% due to the retention of biodegradable compounds during the extraction process. Regardless of this drop, the anaerobic digestion is a suitable technology for the stabilization of the different generated residual phases, whereas the high market price of the extracted phenols can largely compensate the slight decrease in the methane generation.
橄榄油生产是许多地中海地区的一个重要工业部门,但目前正面临着必须妥善利用橄榄压榨固体废物(即油渣)的问题。油渣是在橄榄两次压榨提取过程中产生的主要副产物,占初始橄榄质量的 80%左右。油渣是有价值化合物的来源,如橄榄渣油或极有趣的酚类化合物。在本研究中,采用了一种新的生物炼制方法来回收酚类化合物。然而,这些有价值化合物的提取会产生不同的富含有机物的废物质,需要进行处理。
本研究评估了一种新型生物炼制方法中不同馏分的厌氧生物降解性,该方法用于油渣的整体增值。结果表明,在油渣生物炼制过程中获得的不同相可以有效地进行厌氧消化,并且没有检测到抑制过程。在两个月的储存后,获得的悬浮固体相和无悬浮固体的液相的甲烷产率系数最高,分别为 366 ± 7 mL CH/g VS 和 358 ± 6 mL CH/g VS。
由于在提取过程中保留了可生物降解的化合物,酚类提取过程降低了甲烷产率系数约 25%。尽管产量下降,但厌氧消化是稳定不同产生的残余相的合适技术,而提取出的高市场价格的酚类化合物可以大大弥补甲烷生成的少量减少。