National Center for NanoScience and Technology, University of Chinese Academy of Sciences, No. 11 Zhongguancun Beiyitiao, Beijing, 100190, P. R. China.
Department of Biomedical Engineering, Southern University of Science and Technology, No 1088, Xueyuan Rd., Xili, Nanshan District, Shenzhen, Guangdong, 518055, P. R. China.
Small. 2020 Dec;16(51):e2005336. doi: 10.1002/smll.202005336. Epub 2020 Nov 25.
Highly stretchable, conductive, biocompatible conductors, and connectors are crucial for the fabrication of flexible devices. However, it remains a problem to get highly stretchable, conductive materials with low cost on a large scale. Another problem in production is the connection between soft and rigid components. Here, a new conductive nanocomposite is reported by mixing the 11-mercaptoundecanoic acid (MUA) modified liquid metal (LM) nanoparticles with polystyrene-block-polybutadiene-block-polystyrene (SBS), which is biocompatible (in vivo and in vitro), conductive (12 000 S cm of conductivity), and stretchable (800% of elongation). Apart from its good performance, this material can be produced on a large scale by using a commercial polymer product and a straightforward physical production process. MUA is used to compromise the dense "gallium oxide shell" of liquid metal nanoparticles such that the whole composite can become conductive. By using resin to modify this composite, this new conductive material can be adhesive and highly conductive, and serve as a stable and efficient connector between soft conductor and rigid component.
高拉伸、导电、生物兼容的导体和连接器对于制造柔性设备至关重要。然而,在大规模生产中获得具有低成本、高拉伸性能的导电材料仍然是一个问题。生产过程中的另一个问题是软质和硬质组件之间的连接。在这里,通过将 11-巯基十一酸(MUA)修饰的液态金属(LM)纳米颗粒与聚苯乙烯-嵌段-聚丁二烯-嵌段-聚苯乙烯(SBS)混合,报告了一种新型导电纳米复合材料,该材料具有生物兼容性(体内和体外)、导电性(12000 S cm 的电导率)和拉伸性(800%的伸长率)。除了性能良好之外,这种材料还可以通过使用商业聚合物产品和简单的物理生产工艺进行大规模生产。MUA 用于折衷液态金属纳米颗粒的密集“氧化镓壳”,使得整个复合材料可以具有导电性。通过使用树脂对这种复合材料进行改性,这种新型导电材料可以具有粘性和高导电性,并作为软导体和硬组件之间稳定高效的连接器。