Huang Wen-Huan, Zhang Xing-Xing, Zhao Yan-Na
Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710129, China.
Dalton Trans. 2021 Jan 7;50(1):15-28. doi: 10.1039/d0dt03524f. Epub 2020 Nov 25.
As a typical group of coordination polymers, metal-organic zeolite (MOZs) frameworks inherit the topological and structural advantages of inorganic zeolites and display great application potential in many areas, including gas adsorption/separation, catalysis, luminescence and chemical sensing. In this review, we outline the recent progress in the synthesis, functionalization and application of metal-organic zeolite frameworks, mainly focusing on the basic structural design principle and synthesis strategy on 4-connect inorganic nodes and 2-connect organic linkers. Employing different valent metals, small inorganic TO units and high-nuclear clusters as 4-connect nodes, we derived multi-types of MOZs with a modified framework charge, improved stability and enhanced photo-/eletrocatalytic activity. Besides, the selection, functionalization and defect-engineering on the 2-connect ligands generated different topological and functional MOZs. Finally, the future trends and some perspectives in this area are outlined.
作为一类典型的配位聚合物，金属有机沸石（MOZs）框架继承了无机沸石的拓扑和结构优势，并在许多领域展现出巨大的应用潜力，包括气体吸附/分离、催化、发光和化学传感。在本综述中，我们概述了金属有机沸石框架在合成、功能化和应用方面的最新进展，主要聚焦于四连接无机节点和二连接有机配体的基本结构设计原则和合成策略。通过使用不同价态的金属、小型无机TO单元和高核簇作为四连接节点，我们得到了多种类型的MOZs，它们具有修饰后的框架电荷、更高的稳定性以及增强的光/电催化活性。此外，对二连接配体的选择、功能化和缺陷工程产生了不同拓扑结构和功能的MOZs。最后，概述了该领域的未来趋势和一些观点。
