Synthesis of photodegradable cassava starch-based double network hydrogel with high mechanical stability for effective removal of methylene blue.

Synthetic hydrogel has been widely used in several applications, but poor mechanical stability and biodegradability limit their applications and raise environmental concerns. Here, a biodegradable hydrogel was developed via simple free-radical polymerization of poly(acrylic acid) (PAA) in the presence of cassava starch (CS) and poly(vinyl alcohol). The hydrogel showed exceptional mechanical and physical properties. The structural morphology changed at higher CS content from a dense fiber-like porous network to larger pores with thicker cell walls. Due to the formation of a double network structure via physical entanglement, the compressive modulus significantly increased from 27 kPa (CS 0 wt%) to 127 kPa (CS 50 wt%). Reducing synthetic content (PAA) to 25 wt% and increasing CS content to 50 wt% did not reduce the removal efficiency of the hydrogel toward methylene blue (MB). The maximum adsorption capacity of the CS50 hydrogel was 417.0 mg/g. Data fitting to theoretical models indicated monolayer adsorption of MB on a homogeneous surface via chemisorption. Removal efficiency was higher than 70% at the 5 cycle of adsorption-desorption. The biodegradability and photodegradability of the hydrogel were improved by grafting with CS. The developed hydrogel represents an alternative biodegradable adsorbent for a sustainable system of wastewater treatment.