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用于可视化和可循环监测铜的比率型探针修饰的荧光传感膜。

Fluorescent sensing film decorated with ratiometric probe for visual and recyclable monitoring of Cu.

作者信息

Jin Xilang, Ma Xuehao, Zhong Wei, Cao Yixin, Zhao Huaqi, Leng Xin, Yang Jingjing, Zhou Hongwei, She Mengyao

机构信息

School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710032, Shaanxi, China.

School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710032, Shaanxi, China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2021 Mar 15;249:119217. doi: 10.1016/j.saa.2020.119217. Epub 2020 Nov 16.

Abstract

Specifically, visually, and quantitatively monitor copper ion (Cu) is critical in the area of biological and environmental detection. Herein, a ratiometric fluorescent probe with benzoxazole appended xanthenes skeleton was constructed and further employed to monitor Cu in Hela cells, real water samples, and test strips. An easily distinguishable colorimetric (colorless to red) and fluorescence (green to red) change could be observed by naked eye under the portable UV lamp (365 nm) and the changes could be recovered by adding S. Furthermore, electrospinning technique was employed to fabricate a probe composited fluorescent sensing film (PMMA) for realizing the visual and recyclable monitoring of Cu, indicating that the probe-composited fluorescent sensing film has great potential for on-site and naked-eye detection of Cu in practical.

摘要

具体而言,在生物和环境检测领域,对铜离子(Cu)进行可视化和定量监测至关重要。在此,构建了一种具有苯并恶唑附加氧杂蒽骨架的比率荧光探针,并进一步用于监测HeLa细胞、实际水样和测试条中的铜。在便携式紫外灯(365 nm)下,肉眼可观察到明显的比色(无色至红色)和荧光(绿色至红色)变化,加入硫后变化可恢复。此外,采用静电纺丝技术制备了一种复合探针的荧光传感膜(聚甲基丙烯酸甲酯),以实现对铜的可视化和可回收监测,这表明该复合探针的荧光传感膜在实际中对铜进行现场和肉眼检测具有巨大潜力。

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