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贵金属表面上钴原子零偏压异常起源的新观点。

A new view on the origin of zero-bias anomalies of Co atoms atop noble metal surfaces.

作者信息

Bouaziz Juba, Mendes Guimarães Filipe Souza, Lounis Samir

机构信息

Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, Jülich, 52425, Germany.

出版信息

Nat Commun. 2020 Nov 30;11(1):6112. doi: 10.1038/s41467-020-19746-1.

Abstract

Many-body phenomena are paramount in physics. In condensed matter, their hallmark is considerable on a wide range of material characteristics spanning electronic, magnetic, thermodynamic and transport properties. They potentially imprint non-trivial signatures in spectroscopic measurements, such as those assigned to Kondo, excitonic and polaronic features, whose emergence depends on the involved degrees of freedom. Here, we address systematically zero-bias anomalies detected by scanning tunneling spectroscopy on Co atoms deposited on Cu, Ag and Au(111) substrates, which remarkably are almost identical to those obtained from first-principles. These features originate from gaped spin-excitations induced by a finite magnetic anisotropy energy, in contrast to the usual widespread interpretation relating them to Kondo resonances. Resting on relativistic time-dependent density functional and many-body perturbation theories, we furthermore unveil a new many-body feature, the spinaron, resulting from the interaction of electrons and spin-excitations localizing electronic states in a well defined energy.

摘要

多体现象在物理学中至关重要。在凝聚态物质中,它们的标志在跨越电子、磁、热力学和输运性质的广泛材料特性方面相当显著。它们可能在光谱测量中留下非平凡的特征,例如那些归因于近藤、激子和极化子特征的特征,其出现取决于所涉及的自由度。在这里,我们系统地研究了通过扫描隧道光谱在沉积于铜、银和金(111)衬底上的钴原子上检测到的零偏置异常,这些异常显著地几乎与从第一性原理获得的异常相同。这些特征源于由有限磁各向异性能量诱导的带隙自旋激发,这与通常将它们与近藤共振相关联的广泛解释形成对比。基于相对论含时密度泛函和多体微扰理论,我们进一步揭示了一种新的多体特征,即自旋子,它是由电子与自旋激发相互作用产生的,这种相互作用将电子态局域在一个明确的能量范围内。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4836/7705691/4d5b1853d457/41467_2020_19746_Fig1_HTML.jpg

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