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拜耳赤泥改性水泥净浆与骨料界面过渡区粘结强度及微观结构研究

Investigation of the bond strength and microstructure of the interfacial transition zone between cement paste and aggregate modified by Bayer red mud.

作者信息

Li Xianhai, Zhang Qin, Mao Song

机构信息

College of Materials and Metallurgy, Guizhou University, Guiyang, 550025, China; Mining College, Guizhou University, Guiyang, 550025, China; National & Local Joint Laboratory of Engineering for Effective Utilization of Regional Mineral Resources from Karst Areas, Guiyang, 550025, China; Guizhou Key Lab of Comprehensive Utilization of Non-metallic Mineral Resources, Guizhou University, Guiyang, 550025, China.

Mining College, Guizhou University, Guiyang, 550025, China; National & Local Joint Laboratory of Engineering for Effective Utilization of Regional Mineral Resources from Karst Areas, Guiyang, 550025, China; Guizhou Key Lab of Comprehensive Utilization of Non-metallic Mineral Resources, Guizhou University, Guiyang, 550025, China.

出版信息

J Hazard Mater. 2021 Feb 5;403:123482. doi: 10.1016/j.jhazmat.2020.123482. Epub 2020 Jul 15.

Abstract

In this study, a method is proposed for modifying aggregate with Bayer red mud (RM), and the bond strength and microstructure of the interfacial transition zone (ITZ) in the concrete prepared using the modified aggregate is determined. Compared to concrete prepared using natural basalt aggregate, concrete prepared with RM-modified basalt aggregate aged for 7 and 28 days had a 25.08 % and 21.75 %, respectively, higher compressive strength and a 39.53 % and 15.30 %, respectively, flexural strength. Compared to concrete prepared using natural limestone aggregate, the compressive and flexural strengths of concrete prepared with RM-modified limestone aggregate increased by over 10.00 % and 20 % respectively, after aging of both 7 and 28 days. The RM had a higher wettability to cement paste than basalt and limestone, implying that cement paste on the surface of RM-modified aggregate had a correspondingly stronger microflow and filling capacity. In addition, concrete prepared with the RM-modified aggregate had a low voidage, a compact ITZ structure and strong interfacial adhesion, resulting in considerably enhanced mechanical properties. This study provides novel applications for RM that can be widely used in building materials and waste reduction and a new method for improving the mechanical properties of concrete.

摘要

本研究提出了一种用拜耳法赤泥(RM)改性骨料的方法,并测定了使用改性骨料制备的混凝土中界面过渡区(ITZ)的粘结强度和微观结构。与使用天然玄武岩骨料制备的混凝土相比,用RM改性玄武岩骨料养护7天和28天制备的混凝土抗压强度分别提高了25.08%和21.75%,抗折强度分别提高了39.53%和15.30%。与使用天然石灰石骨料制备的混凝土相比,用RM改性石灰石骨料养护7天和28天后,制备的混凝土抗压强度和抗折强度分别提高了10.00%以上和20%以上。RM对水泥浆体的润湿性高于玄武岩和石灰石,这意味着RM改性骨料表面的水泥浆体具有相应更强的微流动和填充能力。此外,用RM改性骨料制备的混凝土孔隙率低,ITZ结构致密,界面粘结力强,从而显著提高了力学性能。本研究为RM在建筑材料中的广泛应用和减少废弃物提供了新的途径,也为提高混凝土力学性能提供了一种新方法。

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