A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent.

Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1-imidazol-3-ium chloride () resulted in the formation of the first structurally characterized imidazole-based radical . was established as a single electron transfer reagent by treating it with an acceptor molecule tetracyanoethylene. Moreover, radical was utilized as an organic electron donor in a number of organic transformations such as in activation of an aryl-halide bond, alkene hydrosilylation, and in catalytic reduction of CO to methoxyborane, all under ambient temperature and pressure.