Photoredox radical borylation of electron-deficient alkenes with NHC-boranes.

An efficient photoredox radical borylation of electron-deficient Morita-Baylis-Hillman type alkenes is achieved to afford multi-functionalized allylic boranes. The reaction demonstrates a wide substrate scope and showcases excellent functional group tolerance. It has advantages over the traditional ionic hydroboration methods in the construction of allylic boranes in terms of simple operation, mild conditions, and step-economy.