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用于痕量一氧化氮检测的全喷墨打印介孔氧化锡基超灵敏气体传感器

Fully Inkjet-Printed Mesoporous SnO-Based Ultrasensitive Gas Sensors for Trace Amount NO Detection.

作者信息

Devabharathi Nehru, M Umarji Arun, Dasgupta Subho

机构信息

Department of Materials Engineering, Indian Institute of Science (IISc), C V Raman Avenue, Bangalore, Karnataka 560012, India.

Materials Research Centre, Indian Institute of Science (IISc), C V Raman Avenue, Bangalore, Karnataka 560012, India.

出版信息

ACS Appl Mater Interfaces. 2020 Dec 23;12(51):57207-57217. doi: 10.1021/acsami.0c14704. Epub 2020 Dec 8.

Abstract

Printed sensors are among the most successful groups of devices within the domain of printed electronics, both in terms of their application versatility and the emerging market share. However, reports on fully printed gas sensors are rare in the literature, even though it can be an important development toward fully printed multisensor platforms for diagnostics, process control, and environmental safety-related applications. In this regard, here, we present the traditional tin oxide-based completely inkjet-printed co-continuous and mesoporous thin films with an extremely large surface-to-volume ratio and then investigate their NO sensing properties at low temperatures. A method known as evaporation-induced self-assembly (EISA) has been mimicked in this study using pluronic F127 (PEO-PPO-PEO) as the soft templating agent and xylene as the micelle expander to obtain highly reproducible and spatially homogeneous co-continuous mesoporous crystalline SnO with an average pore diameter of the order of 15-20 nm. The fully printed SnO gas sensors thus produced show high linearity for NO detection, along with extremely high average response of 11,507 at 5 ppm NO. On the other hand, the sensors show an ultralow detection limit of the order of 20 ppb with an easy to amplify response of 31. While the excellent electronic transport properties along such co-continuous, mesoporous structures are ensured by their well-connected (co-continuous) ligaments and pores (thereby ensuring high surface area and high mobility transport at the same time) and may actually be responsible for the outstanding sensor performance that has been observed, the use of an industrial printing technique ascertains the possibility of high-throughput manufacturing of such sensor units toward inexpensive and wide-range applications.

摘要

就其应用的多功能性和新兴的市场份额而言,印刷传感器是印刷电子领域中最成功的一类器件。然而,尽管全印刷气体传感器对于用于诊断、过程控制和环境安全相关应用的全印刷多传感器平台可能是一项重要进展,但文献中关于全印刷气体传感器的报道却很少。在这方面,我们在此展示了基于传统氧化锡的完全喷墨印刷的共连续且具有极大表面体积比的介孔薄膜,然后研究了它们在低温下对一氧化氮(NO)的传感特性。在本研究中,模仿了一种称为蒸发诱导自组装(EISA)的方法,使用普朗尼克F127(聚环氧乙烷 - 聚环氧丙烷 - 聚环氧乙烷)作为软模板剂,二甲苯作为胶束膨胀剂,以获得具有平均孔径约为15 - 20纳米的高度可重复且空间均匀的共连续介孔晶体SnO。由此制备的全印刷SnO气体传感器对NO检测显示出高线性,在5 ppm NO时平均响应极高,达到11,507。另一方面,这些传感器显示出超低检测限,约为20 ppb,且响应易于放大,为31。虽然通过其连接良好(共连续)的韧带和孔隙确保了沿此类共连续介孔结构具有优异的电子传输特性(从而同时确保高表面积和高迁移率传输),并且这实际上可能是观察到的出色传感器性能的原因,但使用工业印刷技术确定了高通量制造此类传感器单元以实现廉价和广泛应用的可能性。

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