Yuan Chao, Zhan Wei, Cui Bo, Yu Bin, Liu Pengfei, Wu Zhengzong
State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China; School of Food Science and Engineering, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China.
State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China; School of Food Science and Engineering, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China.
Food Res Int. 2020 Dec;138(Pt A):109666. doi: 10.1016/j.foodres.2020.109666. Epub 2020 Sep 18.
The physicochemical properties of κ-carrageenan (KC) can be improved by incorporation with small-molecule cosolvents. The texture and rheological properties, micromorphology, and crystallinity of KC incorporating indigestible dextrin (IDD) and beta-limit dextrin (BLD) were investigated. The rheological properties and sol-gel transition temperatures of the gels were slightly improved and the hardness of KC gels was significantly increased after the two dextrins were mixed in. Fourier transform infrared spectroscopy results indicated hydrogen-bonding interactions were strengthened in the presence of the dextrins. Confocal laser scanning microscope images revealed that a more homogenous structure was formed of the KC gel after the addition of dextrins. Moreover, X-ray diffraction patterns indicated the crystallinity of KC gel decreased upon dextrin addition. At the same dextrin content, IDD exerted a greater influence than BLD. IDD contents exceeding 3% (w/w) led to undesirable effects, whereas up to 5% (w/w) of BLD could be added. The two dextrins affected the rearrangement of the KC random coils in the sol state, and facilitated aggregation of the KC chains during cooling to form gel network structures after gelation. Therefore, the appropriate addition of these two dextrins can improve the texture and stability of KC gels and expand their application in functional foods.
κ-卡拉胶(KC)的物理化学性质可通过与小分子助溶剂混合来改善。研究了添加难消化糊精(IDD)和β-极限糊精(BLD)的KC的质地和流变性质、微观形态及结晶度。在混入两种糊精后,凝胶的流变性质和溶胶-凝胶转变温度略有改善,且KC凝胶的硬度显著增加。傅里叶变换红外光谱结果表明,在糊精存在下氢键相互作用增强。共聚焦激光扫描显微镜图像显示,添加糊精后KC凝胶形成了更均匀的结构。此外,X射线衍射图谱表明,添加糊精后KC凝胶的结晶度降低。在相同的糊精含量下,IDD的影响比BLD更大。IDD含量超过3%(w/w)会产生不良影响,而BLD的添加量可达5%(w/w)。这两种糊精影响了溶胶状态下KC无规线团的重排,并在冷却过程中促进了KC链的聚集,从而在凝胶化后形成凝胶网络结构。因此,适当添加这两种糊精可以改善KC凝胶的质地和稳定性,并扩大其在功能性食品中的应用。