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用于柔性有机发光二极管的溶液处理PEDOT:PSS:GO/Ag NWs复合电极

Solution-processed PEDOT:PSS:GO/Ag NWs composite electrode for flexible organic light-emitting diodes.

作者信息

Du Hui, Guo Yangyang, Cui Dongyue, Li Shuhong, Wang Wenjun, Liu Yunlong, Yao Yicun, Zhao Ling, Dong Xiaochen

机构信息

School of Physical Science and Information Technology, Liaocheng University, Shandong 252059, China; Shandong Provincial Key Laboratory of Optical Communication Science and Technology, Shandong 252059, China.

School of Physical Science and Information Technology, Liaocheng University, Shandong 252059, China; Shandong Provincial Key Laboratory of Optical Communication Science and Technology, Shandong 252059, China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2021 Mar 5;248:119267. doi: 10.1016/j.saa.2020.119267. Epub 2020 Dec 1.

Abstract

Flexible organic light emitting diodes (OLEDs) have attracted considerable attention for the reason of light weight, high mechanical flexibility in display and lighting. The most widely used transparent anode indium tin oxide (ITO) is unsuitable for flexible OLEDs because of its easy cracking upon bending. In this paper, we proposed a simple two steps solution processing method to fabricate flexible PEDOT:PSS:GO/Ag NWs composite electrodes. The optimized PEDOT:PSS:GO/Ag NWs composite electrode exhibits an optical transmittance of 88.7% at a wavelength of 550 nm and a low sheet resistance of 17 Ω/sq, which arecomparable to that of ITO. With PEDOT:PSS:GO/Ag NWs composite electrodes, the turn on voltage, current density and maximum brightness of OLEDs based on composite electrode were 2.1 V, 6.2 cd/A and 22894 cd/m, respectively, which were superior to that OLED based on ITO anode. The enhanced performance of OLEDs based on composite anode mainly attributed to the lower sheet resistance, smoother surface of the composite anode and the far surface plasma resonance (Far SPR) effect, a lower waveguide optical loss because of the introduction of Ag NWs in the electrode.

摘要

柔性有机发光二极管(OLED)因其重量轻、在显示和照明方面具有高机械柔韧性而备受关注。最广泛使用的透明阳极氧化铟锡(ITO)由于在弯曲时容易开裂,不适用于柔性OLED。在本文中,我们提出了一种简单的两步溶液处理方法来制备柔性聚(3,4-乙撑二氧噻吩):聚苯乙烯磺酸盐:氧化石墨烯/银纳米线(PEDOT:PSS:GO/Ag NWs)复合电极。优化后的PEDOT:PSS:GO/Ag NWs复合电极在550纳米波长处的透光率为88.7%,方阻为17Ω/sq,与ITO相当。使用PEDOT:PSS:GO/Ag NWs复合电极时,基于复合电极的OLED的开启电压、电流密度和最大亮度分别为2.1V、6.2cd/A和22894cd/m²,优于基于ITO阳极的OLED。基于复合阳极的OLED性能增强主要归因于复合阳极的低方阻、更光滑的表面和远表面等离子体共振(Far SPR)效应,以及由于在电极中引入银纳米线而导致的较低波导光损耗。

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