Co-release potential and human health risk of heavy metals from galvanized steel pipe scales under stagnation conditions of drinking water.

The re-release of heavy metals accumulated in the drinking water distribution systems (DWDSs) may pose a significant threat to water quality and human health. In this work, the pipe scales in the actual DWDS were collected, and their physicochemical characteristics were investigated by SEM, XRF, XRD, XPS, and sequential extraction procedure. The co-release potential of heavy metals under different scale dosages, temperatures, and stagnation times was explored by stagnation release tests. Pearson correlation analysis on metal release and human health risk assessment was used to reveal the inter-metal correlation and potential risk of metal release. The results showed that the metal release potential under stagnation water conditions arose primarily from the acid-soluble fraction. The chronic non-carcinogenic risk of soluble metals followed the order: Mn > Fe > Zn > Pb. The risk caused by the soluble metal release could be ignored (HI < 1, HI: hazard index) under normal stagnation times (within 8 h). The major finding of this work was that Ca and Mn were more labile to release and had a significant linear co-release correlation (scale powder: R = 0.906, p < 0.01; pipe section: R = 0.982, p < 0.01), which indicated their co-existence and linear co-release. Ca was recognized as the "major metal" that affected the release of trace metals. The health risk probably increased with the release of Ca, which could also be used as an "indicator" of Mn release.