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Ag 和 Pd 纳米颗粒的绿色合成及其在水污染物处理中的应用。

Green synthesis of Ag and Pd nanoparticles for water pollutants treatment.

机构信息

Biofuels Institute, School of Environment and Safety Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China E-mail:

出版信息

Water Sci Technol. 2020 Dec;82(11):2344-2352. doi: 10.2166/wst.2020.498.

Abstract

Silver (Ag) and palladium (Pd) nanoparticles were synthesized via a green synthesis route, which was mediated with the extract of Daucus carota leaves. The morphological, crystalline and structural nature of the synthesized nanoparticles was characterized by UV-Vis spectrophotometer, and TEM, XRD and FT-IR analyses. High antibacterial activities of the prepared Ag and Pd nanoparticles were observed towards different water-borne pathogens of Klebsiella pneumonia, Vibrio cholera and Escherichia coli. The catalytic efficiency of the prepared nanoparticles for the removal of rhodamine 6G (Rh-6G) dye was also evaluated. Nearly 98% of the Rh-6G dye was decolorized by the synthesized Pd nanoparticles within 2 min, and the synthesized Ag nanoparticles took 30 min for 89.4% decolorization. This work provided greener nanocatalysts for pollutant treatment and demonstrated the power of green biosynthesis for metallic nanoparticles.

摘要

银(Ag)和钯(Pd)纳米粒子通过绿色合成路线合成,该路线由胡萝卜叶提取物介导。通过紫外可见分光光度计、TEM、XRD 和 FT-IR 分析对合成纳米粒子的形态、晶体和结构性质进行了表征。所制备的 Ag 和 Pd 纳米粒子对不同水传播病原体肺炎克雷伯菌、霍乱弧菌和大肠杆菌表现出高抗菌活性。还评估了所制备的纳米粒子对罗丹明 6G(Rh-6G)染料去除的催化效率。合成的 Pd 纳米粒子在 2 分钟内几乎将 98%的 Rh-6G 染料脱色,而合成的 Ag 纳米粒子则需要 30 分钟才能达到 89.4%的脱色率。这项工作为污染物处理提供了更环保的纳米催化剂,并展示了绿色生物合成在金属纳米粒子方面的强大功能。

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