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批次式中温厌氧消化废山羊垫料和山羊奶酪乳清:与两种单一底物的单消化比较。

Batch mesophilic anaerobic co-digestion of spent goat batch mesophilic anaerobic co-digestion of spent goat straw bedding and goat cheese whey: Comparison with the mono-digestion of the two sole substrates.

机构信息

Instituto de la Grasa (CSIC), Campus Universidad Pablo de Olavide, Edificio 46. Ctra. de Utrera Km. 1, 41013, Sevilla, Spain; Departamento de Sistemas Físicos y Naturales, Universidad Pablo de Olavide, Ctra.de Utrera, km 1, 41013, Sevilla, Spain.

Instituto de la Grasa (CSIC), Campus Universidad Pablo de Olavide, Edificio 46. Ctra. de Utrera Km. 1, 41013, Sevilla, Spain.

出版信息

J Environ Manage. 2021 Feb 15;280:111733. doi: 10.1016/j.jenvman.2020.111733. Epub 2020 Dec 24.

Abstract

Spent livestock bedding is a valuable resource for the production of green energy (methane) in rural areas. Comparison and evaluation of batch anaerobic digestion and co-digestion of different mixtures of goat straw bedding (SGSB) and goat cheese whey were carried out. Biochemical methane potential (BMP) tests of the 100% SGSB, 95% SGSB-5% whey, 90% SGSB-10% whey, 85% SGSB-15% whey and 100% whey were found to be 423 ± 7, 354 ± 9, 371 ± 2, 293 ± 1, 274 ± 2 mL CH g VS. Two different kinetic models were evaluated. The logistic model revealed a decrease in the maximum methane production rate (R) from 34.7 ± 1.5 to 14.1 ± 0.9 mL CH g VS·d when the percentage of whey in the mixture increased from 0 to 15% as a consequence of the increased ammonia released during the co-digestion of increased concentrations of whey. The lowest value for the maximum methane production predicted by the model (P) was found for 100% whey (274 ± 10 mL CH g VS). A two-substrate model was applied to describe the evident existence of rapid and slowly degradable material. Regarding the hydrolysis kinetic constants predicted by this model, considerable increases in the rapid biodegradation stage (k) were observed when comparing to the values found for the slow (k) biodegradation stage in all the cases tested. The increases between both constants rose from 5 to 42% when the percentage of whey increased.

摘要

利用牲畜垫料生产沼气是农村地区绿色能源(甲烷)的一种宝贵资源。本文比较和评估了不同比例山羊秸秆垫料(SGSB)和山羊奶酪乳清混合物的批量厌氧消化和共消化。100%SGSB、95%SGSB-5%乳清、90%SGSB-10%乳清、85%SGSB-15%乳清和 100%乳清的生物化学甲烷潜力(BMP)测试值分别为 423±7、354±9、371±2、293±1、274±2 mL CH g VS。评估了两种不同的动力学模型。逻辑模型表明,随着混合物中乳清比例从 0 增加到 15%,最大甲烷产率(R)从 34.7±1.5 降至 14.1±0.9 mL CH g VS·d,这是由于共消化过程中氨的释放增加,导致快速甲烷产生率降低。模型预测的最大甲烷产量(P)的最低值出现在 100%乳清(274±10 mL CH g VS)。应用双底物模型来描述快速和缓慢降解物质的明显存在。关于该模型预测的水解动力学常数,在所有测试的情况下,与慢速(k)生物降解阶段的数值相比,快速生物降解阶段(k)的数值都有相当大的增加。当乳清百分比增加时,两个常数之间的增加幅度从 5%到 42%不等。

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