Interrelated effects of soils and compounds on persulfate oxidation of petroleum hydrocarbons in soils.

Persulfate-based chemical oxidation of petroleum hydrocarbons (TPHs) in soils usually varies drastically with soil sites. Complex effects of soil components on persulfate oxidation of TPHs remains poorly understood, impeding the understanding of persulfate oxidation in practical systems. Here we provided empirical evidence for the interrelated effects of natural soils components and target TPHs on persulfate oxidation of TPHs. Inputs of TPHs led to notable alterations of organic matter, minerals and pH of soils, which in turn influenced distributions and availability of TPHs in soils. These soil/TPH properties and oxidant dose constituted five interrelated terms that were used to develop a predictive model of persulfate oxidation of TPHs. Such interrelation accounted for ilmenite-base coupling activation of persulfate oxidation, Fe/Mn mineral activation of persulfate oxidation, chemical oxidant demand of soils, mass transfer-reactivity limiting of TPHs, and applicable parameters of persulfate oxidation, respectively. The interrelation-based model of persulfate oxidation of TPHs displayed high predictive accuracy of 43% for a factor of 0.3 above and below the ideal fit, despite large differences in contaminated sites and applicable parameters. This finding may have practical interests in the optimization of persulfate oxidation.