Wu Wen-Yuan, Tang Tie-Huan, Li Yi, Xu Shuang
College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211800, China.
Dalton Trans. 2021 Jan 14;50(2):485-489. doi: 10.1039/d0dt03765f. Epub 2020 Dec 24.
An unknown manganese(ii) oxalate complex [MnCO]·0.5HO (1) was discovered with a novel three-dimensional structure, exhibiting versatile bridging modes of the oxalate ligand. The thermal and magnetic behaviors of this complex were studied and the relationship with four other manganese(ii) oxalates is also discussed.