College of Chemical Engineering, Fuzhou University, Fuzhou 350116, P. R. China.
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 Singapore.
ACS Appl Mater Interfaces. 2021 Jan 27;13(3):4740-4749. doi: 10.1021/acsami.0c19704. Epub 2020 Dec 28.
Superhydrophobic conductive materials have received a great amount of interest due to their wide applications in oil-water separation, electrically driven smart surface, electromagnetic shielding, and body motion detection. Herein, a highly conductive superhydrophobic cotton cloth is prepared by a facile method. A layer of polydopamine/reduced graphene oxide (PDA/rGO) was first coated on the cotton fabric, and then copper nanoparticles were in situ grown on the prepared surface. After further modification with stearic acid (STA), the wettability of the cotton surface changed from superhydrophilic to superhydrophobic (water contact angle (WCA) = 153°). The electrical conductivity of the PDA/rGO/Cu/STA cotton is as high as 6769 S·m, while the stearic acid effectively protects Cu NPs from oxidation. As a result, the superhydrophobic PDA/rGO/Cu/STA cotton has shown excellent electrical stability and can be used in detecting human motions in both ambient and underwater conditions. The sensor can recognize human motion from air into water and other underwater activities (e.g., underwater bending, stretching, and ultrasound). This multifunctional cotton device can be used as an ideal sensor for underwater intelligent devices and provides a basis for further research.
超疏水导电材料由于其在油水分离、电驱动智能表面、电磁屏蔽和人体运动检测等方面的广泛应用而受到极大关注。本文通过一种简便的方法制备了一种高导电超疏水棉织物。首先在棉织物上涂覆一层聚多巴胺/还原氧化石墨烯(PDA/rGO),然后在制备的表面上原位生长铜纳米粒子。经过硬脂酸(STA)进一步修饰后,棉表面的润湿性从超亲水变为超疏水(水接触角(WCA)=153°)。PDA/rGO/Cu/STA 棉的电导率高达 6769 S·m,而硬脂酸有效地防止了 Cu NPs 的氧化。因此,超疏水 PDA/rGO/Cu/STA 棉表现出优异的电稳定性,可用于检测人体在空气和水下环境中的运动。该传感器可以识别从空气中进入水中的人体运动以及其他水下活动(例如,水下弯曲、拉伸和超声)。这种多功能棉装置可用作水下智能设备的理想传感器,并为进一步的研究提供了基础。