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氧化石墨烯对聚氨酯/电气石纳米复合纤维的显著影响

Robust Effects of Graphene Oxide on Polyurethane/Tourmaline Nanocomposite Fiber.

作者信息

Zhang Yuanchi, Hu Jinlian

机构信息

Centre for Translational Medicine Research & Development, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China.

Department of Biomedical Engineering, City University of Hong Kong, Kowloon, Hong Kong 999077, China.

出版信息

Polymers (Basel). 2020 Dec 23;13(1):16. doi: 10.3390/polym13010016.

Abstract

The use of energy therapy including tourmaline/negative ions has gained huge popularity due to their long-standing historical evidence in improving human health and the technology development. However, the limitations of tourmaline based polyurethane fibers including the unsatisfied mechanical properties and negative ions releasing performances hind their further applications for wearable energy therapy. In this study, graphene oxide was modified within the polyurethane/tourmaline nanocomposite and then the wet-spinning method was used to prepare the fibers. As expected, the results proved that polyurethane/tourmaline/graphene oxide fiber had enhanced Young's modulus (8.4 MPa) and tensile stain at break (335%). In addition, the number of released negative ions from polyurethane/tourmaline/graphene oxide fiber was significantly improved 17 times and 1.6 times more than that of neat polyurethane fiber and polyurethane/tourmaline fiber, respectively. Moreover, the releasing number of negative ions was significantly decreased after being applying voltage. We envision that the proposed polyurethane/tourmaline/graphene oxide fiber will provide valuable insights into the development of the wearable energy products.

摘要

由于在改善人类健康方面有着长期的历史证据以及技术的发展,包括电气石/负离子在内的能量疗法已广受欢迎。然而,基于电气石的聚氨酯纤维存在局限性,包括机械性能和负离子释放性能不尽人意,这阻碍了它们在可穿戴能量疗法中的进一步应用。在本研究中,氧化石墨烯在聚氨酯/电气石纳米复合材料中进行了改性,然后采用湿纺法制备纤维。正如预期的那样,结果证明聚氨酯/电气石/氧化石墨烯纤维的杨氏模量(8.4兆帕)和断裂伸长率(335%)有所提高。此外,聚氨酯/电气石/氧化石墨烯纤维释放的负离子数量显著提高,分别比纯聚氨酯纤维和聚氨酯/电气石纤维多17倍和1.6倍。而且,施加电压后负离子的释放数量显著减少。我们设想,所提出的聚氨酯/电气石/氧化石墨烯纤维将为可穿戴能量产品的开发提供有价值的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba66/7793061/a1f4ff9173b5/polymers-13-00016-g001.jpg

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