Grażyna Mrówka-Nowotnik, Gancarczyk Kamil, Nowotnik Andrzej, Dychtoń Kamil, Boczkal Grzegorz
Department of Material Science, Rzeszów University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland.
Faculty of Non-Ferrous Metals, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, Poland.
Materials (Basel). 2020 Dec 27;14(1):89. doi: 10.3390/ma14010089.
The continuous increase in the consumption of aluminium and its alloys has led to an increase in the amount of aluminium scrap. Due to environmental protection, and to reduce the costs of manufacturing aluminum in recent years, a lot of research is devoted to recycling of aluminum alloys. The paper presents the results of research concerning the possibility of manufacturing standardized alloy 2017A from commercial and post-production scrap by continuous casting. Obtained from recycling process ingots were subjected to analysis of chemical composition and intermetallic phase composition. Based on the results of light microscopy (LM), scanning electron microscopy + electron dispersive spectroscopy (SEM + EDS), and X-ray diffraction (XRD) the following phases in the as-cast state were identified: θ-AlCu, β-MgSi, AlCuFe, Q-AlCuMgSi, and α-Al(FeMn)(SiCu). During solution heat treatment most of the primary precipitates of intermetallic phases, like θ-AlCu, β-MgSi, and Q-AlCuMgSi, were dissolved in the solid solution α-Al, and during natural and artificial aging they precipitate as strengthening phases θ-AlCu and Q-AlCuMgSi with high dispersion. The highest hardness-150.3 HB-of 2017A alloy was obtained after solution heat treatment from 510 °C and aging at 175 °C. In the static tensile test the mechanical (R and R.) and plastic (A) properties were determined for 2017A alloy in the cast state and after T4 heat treatment. The highest strength properties-tensile strength R = 450.5 MPa and yield strength R. = 268.7 MPa with good relative elongation A = 14.65%, were obtained after solution heat treatment at 510 °C/6 h/water quenching and natural aging at 25 °C for 70 h. The alloy manufactured from recycled scrap is characterized by relatively high mechanical properties.
铝及其合金消费量的持续增长导致了铝废料数量的增加。由于环境保护以及近年来为降低铝的制造成本,大量研究致力于铝合金的回收利用。本文介绍了关于通过连续铸造由商业废料和生产后废料制造标准2017A合金可能性的研究结果。对回收过程中获得的铸锭进行了化学成分和金属间相组成分析。基于光学显微镜(LM)、扫描电子显微镜+电子能谱(SEM+EDS)和X射线衍射(XRD)的结果,确定了铸态下的以下相:θ-AlCu、β-MgSi、AlCuFe、Q-AlCuMgSi和α-Al(FeMn)(SiCu)。在固溶热处理过程中,大多数金属间相的初生析出物,如θ-AlCu、β-MgSi和Q-AlCuMgSi,溶解在α-Al固溶体中,在自然时效和人工时效过程中,它们以高弥散度的强化相θ-AlCu和Q-AlCuMgSi析出。2017A合金在510℃固溶热处理并在175℃时效后获得最高硬度150.3HB。在静态拉伸试验中,测定了2017A合金铸态和T4热处理后的力学性能(R和R)和塑性性能(A)。在510℃/6h/水淬固溶热处理并在25℃自然时效70h后,获得了最高强度性能——抗拉强度R=450.5MPa,屈服强度R=268.7MPa,相对伸长率A=14.65%良好。由回收废料制造的合金具有相对较高的力学性能。