Jiang Long, Zhang Zhifeng, Bai Yuelong, Mao Weimin
National Engineering Research Center for Non-Ferrous Metal Composites, China GRINM Group Co., Ltd., Beijing 100088, China.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Materials (Basel). 2023 Aug 3;16(15):5435. doi: 10.3390/ma16155435.
A weldable Al-Mg-Zn-Sc alloy was produced using vacuum induction melting and an argon-protected casting method to achieve high strength and ductility, and the effects of heat treatment on the microstructure evolution and mechanical properties of Al-Mg-Zn-Sc alloys were comparatively investigated. The results reveal that fine equiaxed grains with an average grain size of 40 μm in an as-cast Al-Mg-Zn-Sc alloy change little after heat treatments, bringing about a grain-boundary strengthening of 46.1 MPa. The coarse T-Mg(Al, Zn) phases at grain boundaries are completely dissolved into the matrix through solid-solution treatment, and T-Mg(Al, Zn) with diameters ranging from 10 to 25 nm and AlSc with diameters ranging from 5 to 20 nm gradually precipitate during the artificial aging process. The Mg solid solubility is 4.67% in the as-cast Al-Mg-Zn-Sc alloy, and it increased to 5.33% after solid-solution treatment and dramatically decreased to 4.15% after post-aging treatment. The contributions of solid-solution strengthening to as-cast, post-solid-solution and post-aging Al-Mg-Zn-Sc alloys are 78.2 MPa, 85.4 MPa and 72.3 MPa, respectively. The precipitation strengthening of the post-aging alloy is 49.7 MPa, which is an increase of 21% in comparison to that of both as-cast and post-solid-solution alloys. The alloy achieves an optimal tensile strength of 355.3 MPa, yield strength of 175 MPa and elongation of 22% after undergoing solid-solution treatment.
采用真空感应熔炼和氩气保护铸造方法制备了一种可焊接的Al-Mg-Zn-Sc合金,以获得高强度和良好的延展性,并对比研究了热处理对Al-Mg-Zn-Sc合金微观组织演变和力学性能的影响。结果表明,铸态Al-Mg-Zn-Sc合金中平均晶粒尺寸为40μm的细小等轴晶粒在热处理后变化不大,产生了46.1MPa的晶界强化效果。晶界处粗大的T-Mg(Al, Zn)相通过固溶处理完全溶解到基体中,在人工时效过程中,直径为10至25nm的T-Mg(Al, Zn)相和直径为5至20nm的AlSc相逐渐析出。铸态Al-Mg-Zn-Sc合金中Mg的固溶度为4.67%,固溶处理后增加到5.33%,时效后显著降低至4.15%。固溶强化对铸态、固溶后和时效后的Al-Mg-Zn-Sc合金的贡献分别为78.2MPa、85.4MPa和72.3MPa。时效后合金的析出强化为49.7MPa,与铸态和固溶后合金相比增加了21%。经过固溶处理后,该合金的抗拉强度达到最佳值355.3MPa,屈服强度为175MPa,伸长率为22%。