原位NHC-钯催化选择性活化β-碳硼烷的B(3)-H或B(6)-H键用于炔烃的硼氢化反应：一种制备烯基-β-碳硼烷的有效方法。
The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)-H or B(6)-H Bonds of -Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl--carboranes.
作者信息
Cao Ke, Xu Tao-Tao, Wu Ji, Zhang Cai-Yan, Wen Xin-Yu, Yang Junxiao
机构信息
State Key Laboratory of Environment-Friendly Energy Materials & School of Material Science and Engineering, Southwest University of Science and Technology, 59 Qinglong Road, Mianyang, Sichuan 621010, People's Republic of China.
出版信息
Inorg Chem. 2021 Jan 18;60(2):1080-1085. doi: 10.1021/acs.inorgchem.0c03203. Epub 2020 Dec 30.
An in situ Pd-NHC catalyzed selective B(3,6)-H activation for hydroboration of internal alkynes has been accomplished under mild conditions. This work offers a facile approach for the synthesis of alkenyl--carboranes and has important reference for selective functionalization of B(3,6)-H bonds.
在温和条件下实现了原位钯-氮杂环卡宾催化的内部炔烃硼氢化反应中B(3,6)-H的选择性活化。这项工作为烯基碳硼烷的合成提供了一种简便的方法，并且对B(3,6)-H键的选择性官能化具有重要的参考意义。
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