Highly efficient, high-energy, picosecond, synchronously pumped Raman laser at 1171 and 1217 nm based on PbMoO crystals with single and combined Raman shifts.

For the first time to our knowledge, the operation of a synchronously pumped ultrafast Raman laser that uses a PbMoO crystal as the active medium has been demonstrated. We achieved efficient Raman conversion in PbMoO from pumping 1063 nm into 1171 and 1217 nm, respectively, at single and combined frequency shifts on stretching and bending Raman modes. The output pulse energy (up to 160 nJ) and peak power (up to 11 kW) of the output picosecond radiation is the highest among all-solid-state synchronously pumped Raman lasers published to date. The strongest pulse shortening at 1217 nm down to 1.4 ps was obtained that is close to the bending mode dephasing time.