Gupta Nitant, Alred John M, Penev Evgeni S, Yakobson Boris I
Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005, United States.
ACS Nano. 2021 Jan 26;15(1):1342-1350. doi: 10.1021/acsnano.0c08588. Epub 2020 Dec 31.
Carbon nanotubes (CNTs) individually display exceptional mechanical properties, but the strength of their mesoscale assemblies such as bundles has a fundamental disconnect, with limited understanding of its scaling. Here we use coarse-grained implementation of a CNT interface with prescribed length distributions and parametrized cross-link density, providing two essential control parameters. It is shown that a linear relationship between strength of the bundles and these control parameters exists, across multiple hierarchies of nanotube interfaces. Furthermore, all geometrical perturbations caused by length distribution and bundle dimensions result in a net stress concentration effect, without influencing the scaling behavior.
碳纳米管(CNTs)各自展现出卓越的机械性能,但其介观组装体(如管束)的强度却存在根本脱节,对其尺度关系的理解有限。在此,我们采用具有规定长度分布和参数化交联密度的碳纳米管界面的粗粒度实现方法,提供了两个关键控制参数。结果表明,在多个纳米管界面层次结构中,管束强度与这些控制参数之间存在线性关系。此外,由长度分布和管束尺寸引起的所有几何扰动都会导致净应力集中效应,而不影响尺度行为。