Department of Food Engineering, Middle East Technical University, 06800 Ankara, Turkey.
Int J Biol Macromol. 2021 Feb 15;170:437-446. doi: 10.1016/j.ijbiomac.2020.12.160. Epub 2020 Dec 28.
Intelligent packaging is important to get information about real time quality of foods. The objective of this study was to develop an electrospun nanofiber halochromic pH sensor film using curcumin, chitosan (CS) and polyethylene oxide (PEO) to monitor chicken freshness. Conductivity and rheological behavior of CS/PEO/curcumin solutions were measured to understand the effect of solution properties on the morphology of the fibers. The morphological characteristics of nanofiber films were investigated by Field Emission Scanning Electron Microscopy (FESEM). Average diameter of the fibers was found to be between 283 ± 27 nm and 338 ± 35 nm. It was concluded that increasing CS amount in nanofibers decreased the diameter of the fibers. Thermal analysis and water vapor permeability features of the pH sensor were also examined. Color changes of curcumin loaded CS/PEO nanofiber film was evaluated on chicken breast package at 4 °C. The color of nanofiber film changed from bright yellow to reddish color which provided an opportunity to detect color changes by even the naked eyes of the untrained consumer. As a quality indicator, surface pH changes of the chicken breast and TVB-N (total volatile basic nitrogen) were measured. At the end of the day 5, pH value of 6.53 ±0.08 and TVB-N concentration of 23.45 ±3.35 mg/100 g indicated that food was at the edge of the acceptance level. As a result, curcumin loaded nanofiber satisfied the expectation and gave an opportunity to visualize real time monitoring of chicken spoilage.
智能包装对于获取食品实时质量信息非常重要。本研究旨在开发一种基于姜黄素、壳聚糖(CS)和聚乙烯氧化物(PEO)的电纺纳米纤维变色 pH 传感器膜,用于监测鸡肉的新鲜度。测量 CS/PEO/姜黄素溶液的电导率和流变行为,以了解溶液性质对纤维形态的影响。通过场发射扫描电子显微镜(FESEM)研究了纳米纤维膜的形态特征。发现纤维的平均直径在 283 ± 27nm 和 338 ± 35nm 之间。结果表明,纳米纤维中 CS 含量的增加会降低纤维的直径。还研究了 pH 传感器的热分析和水蒸气透过性能。评估了姜黄素负载 CS/PEO 纳米纤维膜在 4°C 下鸡胸脯包装上的颜色变化。纳米纤维膜的颜色从亮黄色变为红棕色,这为未经训练的消费者用肉眼检测颜色变化提供了机会。作为质量指标,测量了鸡胸脯的表面 pH 值和 TVB-N(总挥发性碱性氮)的变化。在第 5 天结束时,pH 值为 6.53 ±0.08,TVB-N 浓度为 23.45 ±3.35mg/100g,表明食物处于可接受水平的边缘。因此,姜黄素负载纳米纤维满足了预期,并为可视化实时监测鸡肉腐败提供了机会。