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采用简易构建的钙钛矿结构 BiMoO 电化学传感环境水样中酚类衍生物 4-氰基苯酚

An electrochemical sensing of phenolic derivative 4-Cyanophenol in environmental water using a facile-constructed Aurivillius-structured BiMoO.

机构信息

Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan, ROC.

Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan, ROC.

出版信息

Ecotoxicol Environ Saf. 2021 Jan 15;208:111701. doi: 10.1016/j.ecoenv.2020.111701. Epub 2020 Nov 28.

Abstract

Harmful chemicals are always found in the environment and it is necessary to construct a viable sensor to detect those chemicals. In order to construct an electrochemical sensing platform, designing an electrode using bismuth mixed oxides are more important and which grabbed more attention due to its high electrocatalytic ability and conductivity. In this literature, we report a facile synthesis of thorn apple like structured pure bismuth molybdate (BiMoO) using a simple hydrothermal assisted one-step calcination method and we report a facile method to sense 4-cyanophenol by electrochemical technique. BiMoO modified (Glassy Carbon electrode) GCE possess two linear ranges 0.1-39.1 µM and 46.6-110.1 µM with excellent detection limit 0.008297 µM and 0.01097 µM. Also, this novel sensor is steady with good stability, repeatability, and reproducibility. Successfully, the environmental water sample is analyzed as a real sample with a feasible and quantification results which were compared with HPLC analysis.

摘要

有害化学物质总是存在于环境中,因此有必要构建一种可行的传感器来检测这些化学物质。为了构建电化学传感平台,使用铋混合氧化物设计电极更为重要,由于其高电催化能力和导电性,因此引起了更多关注。在本文中,我们报告了一种简便的合成方法,使用简单的水热辅助一步煅烧法制备了具有刺槐状结构的纯钼酸铋(BiMoO),并报告了一种通过电化学技术检测 4-氰苯酚的简便方法。BiMoO 修饰的(玻碳电极)GCE 具有两个线性范围 0.1-39.1 µM 和 46.6-110.1 µM,具有出色的检测限 0.008297 µM 和 0.01097 µM。此外,该新型传感器具有良好的稳定性、重复性和再现性。成功地分析了环境水样作为实际样品,并与 HPLC 分析进行了比较,得到了可行的定量结果。

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