Hu Xianzhong, Bai Fangchao, Yu Chang, Yan Fusheng
School of Metallurgy, Northeastern University, Shenyang, Liaoning 110819, China.
ACS Omega. 2020 Dec 16;5(51):33372-33379. doi: 10.1021/acsomega.0c05212. eCollection 2020 Dec 29.
The experimental study on the laminar flame speeds of the CH/H/CO/CO/N mixture was carried out in oxygen-enriched air condition. The laminar flame propagation velocities of the blended gas were measured in a range of equivalence ratios (from 0.6 to 1.4) and oxygen concentrations (from 21 to 33%) using a Bunsen flame. Comparisons between the experiments and calculations show that the GRI Mech 3.0 mechanism can well predict the laminar flame speed of the blended gas in oxygen-enriched conditions. The laminar flame propagation velocities were enhanced by the increasing oxygen concentration, while the reaction pathway of fuel changed little. The effects of each species of the CH/H/CO/CO/N mixture on the laminar flame speeds were discussed. Results show that the laminar flame speed is promoted by the increase of H and CO, while the laminar flame speed is decreased by the increasing CH, CO, and N concentrations. The inhibition effect of CO on the laminar flame speed is bigger than that of N, which is due to the difference in the properties of CO and N.
在富氧空气条件下对CH/H/CO/CO/N混合物的层流火焰速度进行了实验研究。使用本生火焰在一系列当量比(从0.6到1.4)和氧气浓度(从21%到33%)范围内测量了混合气体的层流火焰传播速度。实验与计算结果的比较表明,GRI Mech 3.0机理能够很好地预测富氧条件下混合气体的层流火焰速度。层流火焰传播速度随着氧气浓度的增加而提高,而燃料的反应路径变化不大。讨论了CH/H/CO/CO/N混合物中各组分对层流火焰速度的影响。结果表明,H和CO浓度的增加促进了层流火焰速度,而CH、CO和N浓度的增加则降低了层流火焰速度。CO对层流火焰速度的抑制作用大于N,这是由于CO和N的性质不同所致。