Ha Ji-Hwan, Song Hyeonjun, Kim Hyunwoo, Kim Dongearn, Jeong Youngjin, Park Sung-Hoon
Department of Mechanical Engineering, Soongsil University, 369 Sangdo-ro, Donjak-gu, Seoul, 156-743, Korea.
Department of Organic Materials and Fiber Engineering, Soongsil University, 369 Sangdo-ro, Donjak-gu, Seoul, 156-743, Korea.
J Nanosci Nanotechnol. 2021 Mar 1;21(3):1809-1814. doi: 10.1166/jnn.2021.18931.
Heating elements need a rapid heating property and long-term cycle stability when subjected to extreme temperatures. Carbon nanotube-based films can be used as ideal heating units owing to their superior electrical and thermal properties. However, carbon nanotube polymer composites are not appropriate for extreme conditions such as high temperatures (300 °C) due to the poor thermal stability of the polymer matrix. In this study, we fabricated a carbon nanotube web film, comprising heating elements consisting of pure carbon nanotubes, through the direct spinning method. The carbon nanotube web film has a microscale thickness. The carbon nanotube web film showed flexibility at high temperatures, while a fracture occurred in the case of the carbon nanotube polymer composite. We conducted electrical heating experiments on the curved carbon nanotube web film to observe the heating uniformity and flexibility. The heating test is conducted on various curved form heaters. The carbon nanotube web film showed rapid heating properties and a uniform heat distribution (temperature departure of less than 3%) without thermal aggregation. The curved heating units can be utilized in various applications such as functional clothes and de-icing systems having curved surfaces.
加热元件在承受极端温度时需要具备快速加热性能和长期循环稳定性。基于碳纳米管的薄膜因其优异的电学和热学性能,可作为理想的加热单元。然而,由于聚合物基体的热稳定性较差,碳纳米管聚合物复合材料不适用于高温(300°C)等极端条件。在本研究中,我们通过直接纺丝法制备了一种碳纳米管网状薄膜,其加热元件由纯碳纳米管组成。该碳纳米管网状薄膜具有微米级厚度。碳纳米管网状薄膜在高温下表现出柔韧性,而碳纳米管聚合物复合材料则会发生断裂。我们对弯曲的碳纳米管网状薄膜进行了电加热实验,以观察其加热均匀性和柔韧性。加热测试在各种弯曲形状的加热器上进行。碳纳米管网状薄膜表现出快速加热性能和均匀的热分布(温度偏差小于3%),且无热聚集现象。这种弯曲的加热单元可用于各种应用,如具有曲面的功能性服装和除冰系统。