Qin Peng, Chen Yang, Liu Yu-Jing, Zhang Junxi, Chen Liang-Yu, Li Yuhua, Zhang Xuhui, Cao Chongde, Sun Hongqi, Zhang Lai-Chang
School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, Perth, Western Australia 6027, Australia.
Shanghai Key Laboratory of Material Protection and Advanced Material in Electric Power, Shanghai University of Electric Power, Shanghai 200090, China.
ACS Biomater Sci Eng. 2019 Feb 11;5(2):1141-1149. doi: 10.1021/acsbiomaterials.8b01341. Epub 2019 Jan 2.
Distinct corrosion behavior was reported in multiphased titanium alloys prepared by additive manufacturing and by traditional technologies because of different phase constituents formed during processing. An open question is therefore raised: is there always different corrosion behavior of materials prepared by different methods? This work reports resemble corrosion behavior of selective laser melted and wrought single β-phase Ti-24Nb-4Zr-8Sn (Ti2448) in both NaCl solution and Hank's solution. The electrochemical measurements showed that both samples have close calculated polarization resistance and corrosion potential in NaCl solution, i.e., 4.99 ± 0.63 MΩ cm and -0.26 ± 0.01 V for the selective laser-melted Ti2448, and 4.42 ± 0.71 MΩ cm and -0.25 ± 0.01 V for the wrought Ti2448, respectively. Both samples reveal the same variation in weight change after 180-day immersion test in Hank's solution. Such resemblance in corrosion behavior without pitting morphologies is attributed to the formation of monolithic β-phase during processing, which demonstrates that titanium alloys with single phase show comparable corrosion behavior regardless of the manufacturing methods adopted.
由于增材制造和传统技术制备的多相钛合金在加工过程中形成的相成分不同,因此报道了它们具有不同的腐蚀行为。因此,一个悬而未决的问题被提了出来:不同方法制备的材料的腐蚀行为是否总是不同?这项工作报道了选择性激光熔化和锻造的单相β相Ti-24Nb-4Zr-8Sn(Ti2448)在NaCl溶液和Hank's溶液中具有相似的腐蚀行为。电化学测量表明,在NaCl溶液中,两个样品的计算极化电阻和腐蚀电位相近,即选择性激光熔化的Ti2448为4.99±0.63MΩ·cm和-0.26±0.01V,锻造的Ti2448分别为4.42±0.71MΩ·cm和-0.25±0.01V。在Hank's溶液中进行180天浸泡试验后,两个样品的重量变化显示出相同的变化。这种没有点蚀形态的腐蚀行为相似性归因于加工过程中形成的整体β相,这表明单相钛合金无论采用何种制造方法都表现出可比的腐蚀行为。