Nakazato Takumi, Shinokubo Hiroshi, Miyake Yoshihiro
Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan.
Chem Commun (Camb). 2021 Jan 11;57(3):327-330. doi: 10.1039/d0cc07804b. Epub 2021 Jan 7.
Complexation of 1,3,6,8-tetra(2-hydroxyphenyl)-2,7-diazapyrene with boron precursors provided the tetracoordinate diazapyrene boron complexes as separable anti- and syn-isomers. The structural difference of these isomers induces unique properties such as self-association behaviour of the syn-isomer and isomerisation of the anti-isomer in the solution and solid states.
1,3,6,8-四（2-羟基苯基）-2,7-二氮杂芘与硼前体的络合作用产生了四配位二氮杂芘硼配合物，可分离为反式和顺式异构体。这些异构体的结构差异引发了独特的性质，例如顺式异构体的自缔合行为以及反式异构体在溶液和固态中的异构化。
