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室温离子液体中的局部和长程组织

Local and Long-Range Organization in Room Temperature Ionic Liquids.

作者信息

Wang Yufeng, Parvis Fatemeh, Hossain Md Iqbal, Ma Ke, Jarošová Romana, Swain Greg M, Blanchard Gary J

机构信息

Department of Chemistry, Michigan State University, 578 S. Shaw Lane, East Lansing, Michigan 48824, United States.

出版信息

Langmuir. 2021 Jan 19;37(2):605-615. doi: 10.1021/acs.langmuir.9b03995. Epub 2021 Jan 7.

DOI:10.1021/acs.langmuir.9b03995
PMID:33411540
Abstract

Room temperature ionic liquids (RTILs) have a wide range of current and potential applications, in areas ranging from supercapacitor energy storage to sequestration of toxic gas phase species and use as reusable solvents for selected organic reactions. All these applications stem from their unique physical and chemical properties, which remain understood to only a limited extent. Among the issues of greatest importance is the extent to which RTILs exist as dissociated ionic species and the length scales over which some types of organizations are seen to exist in them. In this Invited Feature Article, we review the current understanding of organization in this family of materials, where opportunities lie in terms of deepening our understanding, and what potential applications would benefit from gaining such knowledge.

摘要

室温离子液体(RTILs)在从超级电容器储能到有毒气相物质的隔离以及用作特定有机反应的可重复使用溶剂等领域有着广泛的当前和潜在应用。所有这些应用都源于它们独特的物理和化学性质,而对这些性质的理解目前还很有限。其中最重要的问题之一是RTILs以解离离子形式存在的程度,以及在其中观察到某些类型的组织存在的长度尺度。在这篇特邀专题文章中,我们回顾了目前对这类材料中组织的理解,深化理解的机会所在,以及哪些潜在应用将从获得这些知识中受益。

相似文献

1
Local and Long-Range Organization in Room Temperature Ionic Liquids.室温离子液体中的局部和长程组织
Langmuir. 2021 Jan 19;37(2):605-615. doi: 10.1021/acs.langmuir.9b03995. Epub 2021 Jan 7.
2
Extraction of organic compounds with room temperature ionic liquids.室温离子液体萃取有机化合物。
J Chromatogr A. 2010 Apr 16;1217(16):2268-86. doi: 10.1016/j.chroma.2009.09.011. Epub 2009 Sep 10.
3
Chromatographic and spectroscopic methods for the determination of solvent properties of room temperature ionic liquids.用于测定室温离子液体溶剂性质的色谱和光谱方法。
J Chromatogr A. 2004 May 28;1037(1-2):49-82. doi: 10.1016/j.chroma.2003.10.127.
4
Electrochemical studies of hydrogen chloride gas in several room temperature ionic liquids: mechanism and sensing.几种室温离子液体中氯化氢气体的电化学研究:机理与传感
Phys Chem Chem Phys. 2016 Jan 28;18(4):2488-94. doi: 10.1039/c5cp06656e.
5
Analytical applications of room-temperature ionic liquids: a review of recent efforts.室温离子液体的分析应用:近期研究进展综述
Anal Chim Acta. 2006 Jan 18;556(1):38-45. doi: 10.1016/j.aca.2005.06.038. Epub 2005 Jul 20.
6
Room temperature ionic liquids as emerging solvents for the pretreatment of lignocellulosic biomass.室温离子液体作为新兴溶剂用于预处理木质纤维素生物质。
Biotechnol Bioeng. 2011 Jun;108(6):1229-45. doi: 10.1002/bit.23108.
7
Current-stimulated release of solutes solubilized in water-immiscible room temperature ionic liquids (RTILs).在与水不混溶的室温离子液体(RTILs)中溶解的溶质的电流刺激释放。
J Drug Target. 2010 Dec;18(10):787-93. doi: 10.3109/1061186X.2010.525653.
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Scalable Screening of Soft Matter: A Case Study of Mixtures of Ionic Liquids and Organic Solvents.软物质的可扩展筛选:离子液体与有机溶剂混合物的案例研究
J Phys Chem B. 2019 Feb 14;123(6):1340-1347. doi: 10.1021/acs.jpcb.8b11527. Epub 2019 Jan 31.
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Exploring electrochemical windows of room-temperature ionic liquids: a computational study.探索室温离子液体的电化学窗口:计算研究。
J Phys Chem B. 2012 Oct 4;116(39):11943-52. doi: 10.1021/jp303915c. Epub 2012 Sep 24.
10
Determination of the hydrogen-bonding induced local viscosity enhancement in room temperature ionic liquids via femtosecond time-resolved depleted spontaneous emission.通过飞秒时间分辨受激辐射损耗研究氢键诱导的室温离子液体局部黏度增强。
J Phys Chem A. 2011 Jul 14;115(27):7937-47. doi: 10.1021/jp202391m. Epub 2011 Jun 21.

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