Faculty of Biotechnology and Food Sciences, Department of Chemistry, Slovak University of Agriculture in Nitra, Tr. A. Hlinku 2, 949 76, Nitra, Slovak Republic.
Faculty of Agrobiotechnology and Food Resources, Department of Genetics and Plant Breeding, Slovak University of Agriculture in Nitra, Tr. A. Hlinku 2, 949 76, Nitra, Slovak Republic.
Biol Trace Elem Res. 2021 Nov;199(11):4360-4369. doi: 10.1007/s12011-020-02536-7. Epub 2021 Jan 8.
Allium vegetables belong to the most widespread and commonly grown vegetables in Slovakia. In this study, we dealt with the content of selected heavy metals (Zn, Mn, Cr, Cu, Ni, Pb, and Cd) in cultivated garlic (Záhorský, Lukan, Makoi), onion (Amika, Red Matte, Diamant), and leek (Bavaria, Golem, Tango). We determined the total content of heavy metals (aqua regia), and available-mobile forms of heavy metals (1 M NHNO) in soils. Analytical final procedure was flame AAS. The results were compared with the limit values given by the Law no. 220/2004 (valid in the SR) as well as threshold values proposed by the European Commission (EC) (2006). Gained result showed that the total content of Cd (1.26 mg.kg) as well as the available mobile forms of Cd (0.16 mg.kg) and Pb (0.64 mg.kg) was exceeded on the soil on which Allium species were grown. Determined contents of heavy metals in garlic were in the range of 0.03-0.07 mg Cd.kg FM (fresh matter), 0.02-0.11 mg Pb.kg FM (fresh matter), in onion ranged from ND (not detected) to 0.03 mg Cd.kg FM (fresh matter), 0.09-0.2 mg Pb.kg FM (fresh matter), and in leek were in the range of, 0.07-0.13 mg Cd.kg FM (fresh matter), and 0.3-0.5 mg Pb.kg FM (fresh matter). Based on the obtained BAF values, we can conclude that the genus Allium does not belong to the accumulator of evaluated hazardous metals. Safe food production requires constant monitoring of hazardous metals in raw materials of plant origin, as these metals can have serious negative effects on human health.
葱属蔬菜是斯洛伐克最广泛和普遍种植的蔬菜之一。在这项研究中,我们研究了栽培大蒜(Záhorský、Lukan、Makoi)、洋葱(Amika、Red Matte、Diamant)和韭菜(Bavaria、Golem、Tango)中选定重金属(锌、锰、铬、铜、镍、铅和镉)的含量。我们测定了土壤中重金属的总含量(王水)和重金属的可移动形式(1 M NHNO₃)。分析的最终程序是火焰原子吸收光谱法。结果与第 220/2004 号法律(在 SR 中有效)规定的限量值以及欧洲委员会(EC)(2006 年)提出的阈值进行了比较。结果表明,在种植葱属植物的土壤中,镉的总含量(1.26mg/kg)以及镉和铅的可移动形式(0.16mg/kg 和 0.64mg/kg)都超过了规定的限量值。测定的大蒜中重金属含量在 0.03-0.07mg Cd.kg FM(鲜重)之间,0.02-0.11mg Pb.kg FM(鲜重)之间,洋葱中镉的含量从 ND(未检出)到 0.03mg Cd.kg FM(鲜重)之间,0.09-0.2mg Pb.kg FM(鲜重)之间,韭菜中镉的含量在 0.07-0.13mg Cd.kg FM(鲜重)之间,铅的含量在 0.3-0.5mg Pb.kg FM(鲜重)之间。基于获得的 BAF 值,我们可以得出结论,葱属植物不属于所评估危险金属的积累者。安全的食品生产需要不断监测植物源性原料中危险金属的含量,因为这些金属会对人类健康造成严重的负面影响。