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采用改良蛇形流场的质子交换膜燃料电池规模化研究,其中包含多孔海绵插入物以观察水分子。

Scaling Up Studies on PEMFC Using a Modified Serpentine Flow Field Incorporating Porous Sponge Inserts to Observe Water Molecules.

机构信息

Fuel Cell Research Lab & Department of Mechanical Engineering, Nandha Engineering College, Erode-638052, India.

Fuel Cell Research Lab & Department of Electrical and Electronics Engineering, Nandha Engineering College, Erode-638052, India.

出版信息

Molecules. 2021 Jan 8;26(2):286. doi: 10.3390/molecules26020286.

Abstract

Flooding of the cathode flow channel is a major hindrance in achieving maximum performance from Proton Exchange Membrane Fuel Cells (PEMFC) during the scaling up process. Water accumulated between the interface region of Gas Diffusion Layer (GDL) and rib of the cathode flow field can be removed by the use of Porous Sponge Inserts (PSI) on the ribs. In the present work, the experimental investigations are carried out on PEMFC for the various reaction areas, namely 25, 50 and 100 cm. Stoichiometry value of 2 is maintained for all experiments to avoid variations in power density obtained due to differences in fuel utilization. The experiments include two flow fields, namely Serpentine Flow Field (SFF) and Modified Serpentine with Staggered provisions of 4 mm PSI (4 mm × 2 mm × 2 mm) Flow Field (MSSFF). The peak power densities obtained on MSSFF are 0.420 W/cm, 0.298 W/cm and 0.232 W/cm compared to SFF which yields 0.242 W/cm, 0.213 W/cm and 0.171 W/cm for reaction areas of 25, 50 and 100 cm respectively. Further, the reliability of experimental results is verified for SFF and MSSFF on 25 cm PEMFC by using Electrochemical Impedance Spectroscopy (EIS). The use of 4 mm PSI is found to improve the performance of PEMFC through the better water management.

摘要

在质子交换膜燃料电池(PEMFC)放大过程中,阴极流道的积水是实现最大性能的主要障碍。在阴极流场的肋条上使用多孔海绵插入物(PSI)可以去除在气体扩散层(GDL)界面区域和肋条之间积聚的水。在本工作中,针对各种反应区域(即 25、50 和 100 cm)对 PEMFC 进行了实验研究。为避免由于燃料利用率的差异导致获得的功率密度发生变化,所有实验均保持化学计量比为 2。实验包括两种流动场,即蛇形流动场(SFF)和具有交错式 4mmPSI(4mm×2mm×2mm)流动场(MSSFF)的改进蛇形流动场。与 SFF 相比,MSSFF 在反应面积为 25、50 和 100 cm 时的最大功率密度分别为 0.420 W/cm、0.298 W/cm 和 0.232 W/cm,而 SFF 的最大功率密度分别为 0.242 W/cm、0.213 W/cm 和 0.171 W/cm。此外,通过电化学阻抗谱(EIS)对 SFF 和 MSSFF 在 25 cm PEMFC 上的实验结果进行了可靠性验证。使用 4mmPSI 被发现可以通过更好的水管理来提高 PEMFC 的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c77a/7827057/e8f833015952/molecules-26-00286-g001.jpg

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