Bermúdez Agudelo María Catalina, Hampe Manfred, Reiber Thorsten, Abele Eberhard
Thermal Process Engineering Group (TVT), Institute for Nano- and Microfluidics (NMF), Technical University of Darmstadt, Otto-Berndt-Straße 2, D-64287 Darmstadt, Germany.
Institute of Production Management, Technology and Machine Tools (PTW), Technical University of Darmstadt, Otto-Berndt-Straße 2, D-64287 Darmstadt, Germany.
Materials (Basel). 2020 May 1;13(9):2096. doi: 10.3390/ma13092096.
A high-temperature proton exchange membrane fuel cell (HT-PEMFC) conventionally uses a planar design with carbon-based substrates as the gas diffusion layer (GDL) materials. However, the metal-based substrates allow for alternative designs. In this study, the applicability of porous thin-walled tubular elements made of 316L stainless steel as the anode GDL in a multi-layer tubular HT-PEMFC was investigated. The anode GDLs were fabricated via powder bed fusion using a laser beam (PBF-LB) process with defined porosities (14% and 16%). The morphology of the porous elements was compared using scanning electron microscopy (SEM) micrographs. The influence of the porosity on the fuel cell performance was evaluated through electrochemical characterization and a short-term stability test (45 h) in a commercial test station operated at 160 °C and ambient pressure, using hydrogen as the fuel and air as the oxidant. The results showed that the fuel cell manufactured upon the anode GDL with a porosity of 16% had a higher performance with a peak power density of 329.25 W/m after 5 h of operation at 125.52 A/m and a voltage degradation rate of 0.511 mV/h over the stability test period. Moreover, this work indicates that additive manufacturing could be a useful tool for further fuel cell development.
高温质子交换膜燃料电池(HT - PEMFC)传统上采用平面设计,以碳基材料作为气体扩散层(GDL)。然而,金属基材料可实现其他设计。本研究考察了由316L不锈钢制成的多孔薄壁管状元件作为多层管状HT - PEMFC阳极GDL的适用性。阳极GDL通过激光粉末床熔融(PBF - LB)工艺制造,孔隙率分别为14%和16%。利用扫描电子显微镜(SEM)图像比较了多孔元件的形态。通过电化学表征以及在160°C和常压下运行的商业测试站中进行的短期稳定性测试(45小时),以氢气为燃料、空气为氧化剂,评估了孔隙率对燃料电池性能的影响。结果表明,基于孔隙率为16%的阳极GDL制造的燃料电池性能更高,在125.52 A/m的电流密度下运行5小时后,峰值功率密度为329.25 W/m²,在稳定性测试期间电压降解率为0.511 mV/h。此外,这项工作表明增材制造可能是进一步发展燃料电池的有用工具。