School of Biology, Chemistry and Material Science, East China University of Technology, Nanchang, Jiangxi 344000, China.
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands.
Inorg Chem. 2021 Feb 1;60(3):1310-1314. doi: 10.1021/acs.inorgchem.0c03526. Epub 2021 Jan 15.
Herein, we report a highly rare robust 4d-5f bimetal-organic framework that shows high porosity and thermal/chemical stability and thus is capable of removing trace SO from a SO/CO/N mixture even under humid conditions. This work not only shows a novel adsorbent for SO removal but also extends the function of actinium-based coordination compounds.
在此,我们报道了一种非常罕见的强韧的 4d-5f 双金属有机骨架,它具有高孔隙率和热/化学稳定性,因此即使在潮湿条件下,也能够从 SO/CO/N 混合物中去除痕量的 SO。这项工作不仅展示了一种用于去除 SO 的新型吸附剂,还扩展了基于锕系元素的配位化合物的功能。