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三角体系Sr₃CuSb₂O₉中的无隙量子自旋液体

Gapless Quantum Spin Liquid in the Triangular System Sr_{3}CuSb_{2}O_{9}.

作者信息

Kundu S, Shahee Aga, Chakraborty Atasi, Ranjith K M, Koo B, Sichelschmidt Jörg, Telling Mark T F, Biswas P K, Baenitz M, Dasgupta I, Pujari Sumiran, Mahajan A V

机构信息

Department of Physics, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India.

School of Physical Sciences, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India.

出版信息

Phys Rev Lett. 2020 Dec 31;125(26):267202. doi: 10.1103/PhysRevLett.125.267202.

Abstract

We report gapless quantum spin liquid behavior in the layered triangular Sr_{3}CuSb_{2}O_{9} system. X-ray diffraction shows superlattice reflections associated with atomic site ordering into triangular Cu planes well separated by Sb planes. Muon spin relaxation measurements show that the S=1/2 moments at the magnetically active Cu sites remain dynamic down to 65 mK in spite of a large antiferromagnetic exchange scale evidenced by a large Curie-Weiss temperature θ_{CW}≃-143  K as extracted from the bulk susceptibility. Specific heat measurements also show no sign of long-range order down to 0.35 K. The magnetic specific heat (C_{m}) below 5 K reveals a C_{m}=γT+αT^{2} behavior. The significant T^{2} contribution to the magnetic specific heat invites a phenomenology in terms of the so-called Dirac spinon excitations with a linear dispersion. From the low-T specific heat data, we estimate the dominant exchange scale to be ∼36  K using a Dirac spin liquid ansatz which is not far from the values inferred from microscopic density functional theory calculations (∼45  K) as well as high-temperature susceptibility analysis (∼70  K). The linear specific heat coefficient is about 18  mJ/mol K^{2} which is somewhat larger than for typical Fermi liquids.

摘要

我们报道了层状三角晶格Sr₃CuSb₂O₉体系中的无隙量子自旋液体行为。X射线衍射显示出与原子位置有序化相关的超晶格反射,原子有序排列形成被Sb平面很好分隔的三角Cu平面。μ子自旋弛豫测量表明,尽管从体磁化率中提取的居里 - 外斯温度θ₍CW₎≃ - 143 K表明存在较大的反铁磁交换尺度,但磁活性Cu位点处的S = 1/2磁矩在低至65 mK时仍保持动态。比热测量也表明在低至0.35 K时没有长程序的迹象。5 K以下的磁比热(Cₘ)呈现出Cₘ = γT + αT²的行为。磁比热中显著的T²贡献引发了一种基于具有线性色散的所谓狄拉克自旋子激发的唯象学。根据低温比热数据,我们使用狄拉克自旋液体假设估计主导交换尺度约为36 K,这与从微观密度泛函理论计算推断的值(约45 K)以及高温磁化率分析的值(约70 K)相差不远。线性比热系数约为18 mJ/mol K²,这比典型费米液体的稍大。

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