Yang Ziyi, Wu Yuanbo, Fu Yatong, Yang Jianxin, Lu Jian, Lu Ju-You
Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan Provincial Fine Chemical Engineering Research Center Hainan University, 58 Renmin Road, Haikou 570228, China.
Chem Commun (Camb). 2021 Feb 14;57(13):1655-1658. doi: 10.1039/d0cc07591d. Epub 2021 Jan 19.
A palladium-catalyzed selective B(3)-H arylation of o-carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl-o-carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route for constructing polysubstituted o-carborane derivatives.
利用易于获得的芳基硼酸作为芳基源，已开发出一种在室温下钯催化的邻碳硼烷的选择性B(3)-H芳基化反应，相应的3-芳基邻碳硼烷以良好至优异的产率得到。该方法为构建多取代邻碳硼烷衍生物提供了一条有力的合成路线。
