Ghoshal Dipanwita, Joy Ashwin
Department of Physics, Indian Institute of Technology Madras, Chennai, Tamil Nadu 600036, India.
Phys Rev E. 2020 Dec;102(6-1):062605. doi: 10.1103/PhysRevE.102.062605.
Supercooled liquids display dynamics that are inherently heterogeneous in space. This essentially means that at temperatures below the melting point, particle dynamics in certain regions of the liquid can be orders of magnitude faster than other regions. Often dubbed dynamical heterogeneity, this behavior has fascinated researchers involved in the study of glass transition for over two decades. A fundamentally important question in all glass transition studies is whether one can connect the growing relaxation time to a concomitantly growing length scale. In this paper, we go beyond the realm of ordinary glass forming liquids and study the origin of a growing dynamical length scale ξ in a self-propelled "active" glass former. This length scale, which is constructed using structural correlations, agrees well with the average size of the clusters of slow-moving particles that are formed as the liquid becomes spatially heterogeneous. We further report that the concomitantly growing α-relaxation time exhibits a simple scaling law, τ_{α}∼exp(μξ/T_{eff}), with μ as an effective chemical potential, T_{eff} as the effective temperature, and μξ as the growing free energy barrier for cluster rearrangements. The findings of our study are valid over four decades of persistence times, and hence they could be very useful in understanding the slow dynamics of a generic active liquid such as an active colloidal suspension, or a self-propelled granular medium.
过冷液体表现出在空间上本质上不均匀的动力学特性。这本质上意味着在低于熔点的温度下,液体某些区域的粒子动力学可能比其他区域快几个数量级。这种行为常被称为动力学不均匀性,二十多年来一直吸引着从事玻璃化转变研究的人员。在所有玻璃化转变研究中,一个根本重要的问题是,是否能将不断增长的弛豫时间与相应增长的长度尺度联系起来。在本文中,我们超越了普通玻璃形成液体的范畴,研究了自驱动“活性”玻璃形成体中不断增长的动力学长度尺度ξ的起源。这个长度尺度是利用结构相关性构建的,与随着液体在空间上变得不均匀而形成的慢速移动粒子团簇的平均大小非常吻合。我们进一步报告,相应增长的α弛豫时间呈现出一个简单的标度律,τα∼exp(μξ/Teff),其中μ为有效化学势,Teff为有效温度,μξ为团簇重排的增长自由能垒。我们的研究结果在四个数量级的持续时间内都是有效的,因此对于理解诸如活性胶体悬浮液或自驱动颗粒介质等一般活性液体的慢动力学可能非常有用。