• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过火花放电合成纳米颗粒作为一种制备用于印刷电子的高导电性铂纳米墨水的简便通用技术。

Synthesis of Nanoparticles by Spark Discharge as a Facile and Versatile Technique of Preparing Highly Conductive Pt Nano-Ink for Printed Electronics.

作者信息

Efimov Alexey A, Arsenov Pavel V, Borisov Vladislav I, Buchnev Arseny I, Lizunova Anna A, Kornyushin Denis V, Tikhonov Sergey S, Musaev Andrey G, Urazov Maxim N, Shcherbakov Mikhail I, Spirin Denis V, Ivanov Victor V

机构信息

Moscow Institute of Physics and Technology, National Research University, 141701 Dolgoprudny, Russia.

Kotelnikov Institute of Radioengineering and Electronics of Russian Academy of Sciences, 125009 Moscow, Russia.

出版信息

Nanomaterials (Basel). 2021 Jan 18;11(1):234. doi: 10.3390/nano11010234.

DOI:10.3390/nano11010234
PMID:33477440
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7830501/
Abstract

A cost-effective, scalable and versatile method of preparing nano-ink without hazardous chemical precursors is a prerequisite for widespread adoption of printed electronics. Precursor-free synthesis by spark discharge is promising for this purpose. The synthesis of platinum nanoparticles (PtNPs) using a spark discharge under Ar, N, and air has been investigated to prepare highly conductive nano-ink. The size, chemical composition, and mass production rate of PtNPs significantly depended on the carrier gas. Pure metallic PtNPs with sizes of 5.5 ± 1.8 and 7.1 ± 2.4 nm were formed under Ar and N, respectively. PtNPs with sizes of 18.2 ± 9.0 nm produced using air consisted of amorphous oxide PtO and metallic Pt. The mass production rates of PtNPs were 53 ± 6, 366 ± 59, and 490 ± 36 mg/h using a spark discharge under Ar, N, and air, respectively. It was found that the energy dissipated in the spark gap is not a significant parameter that determines the mass production rate. Stable Pt nano-ink (25 wt.%) was prepared only on the basis of PtNPs synthesized under air. Narrow (about 30 μm) and conductive Pt lines were formed by the aerosol jet printing with prepared nano-ink. The resistivity of the Pt lines sintered at 750 °C was (1.2 ± 0.1)·10 Ω·m, which is about 1.1 times higher than that of bulk Pt.

摘要

一种经济高效、可扩展且通用的制备纳米墨水的方法，且无需使用危险化学前驱体，这是印刷电子广泛应用的前提条件。通过火花放电进行无前驱体合成有望实现这一目标。为了制备高导电性纳米墨水，已对在氩气、氮气和空气中通过火花放电合成铂纳米颗粒（PtNPs）进行了研究。PtNPs的尺寸、化学成分和批量生产率显著取决于载气。在氩气和氮气气氛下分别形成了尺寸为5.5±1.8纳米和7.1±2.4纳米的纯金属PtNPs。使用空气制备的尺寸为18.2±9.0纳米的PtNPs由非晶氧化物PtO和金属Pt组成。在氩气、氮气和空气中通过火花放电制备PtNPs的批量生产率分别为53±6毫克/小时、366±59毫克/小时和490±36毫克/小时。研究发现，火花间隙中耗散的能量不是决定批量生产率的重要参数。仅基于在空气中合成的PtNPs制备了稳定的Pt纳米墨水（25重量%）。使用制备的纳米墨水通过气溶胶喷射印刷形成了狭窄（约30微米）且导电的Pt线。在750℃烧结的Pt线的电阻率为(1.2±0.1)·10Ω·m，约为块状Pt电阻率的1.1倍。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/de4d0e3c7e9f/nanomaterials-11-00234-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/bbd96cedbe13/nanomaterials-11-00234-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/fbb2caaee3c0/nanomaterials-11-00234-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/ba2db78229c8/nanomaterials-11-00234-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/560703062151/nanomaterials-11-00234-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/71f317800e59/nanomaterials-11-00234-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/18ce4510da25/nanomaterials-11-00234-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/102e87d33abe/nanomaterials-11-00234-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/e889dfb972bc/nanomaterials-11-00234-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/5bc6c778cde4/nanomaterials-11-00234-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/eb2a28c9e8c8/nanomaterials-11-00234-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/5c83c38ca112/nanomaterials-11-00234-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/de4d0e3c7e9f/nanomaterials-11-00234-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/bbd96cedbe13/nanomaterials-11-00234-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/fbb2caaee3c0/nanomaterials-11-00234-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/ba2db78229c8/nanomaterials-11-00234-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/560703062151/nanomaterials-11-00234-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/71f317800e59/nanomaterials-11-00234-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/18ce4510da25/nanomaterials-11-00234-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/102e87d33abe/nanomaterials-11-00234-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/e889dfb972bc/nanomaterials-11-00234-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/5bc6c778cde4/nanomaterials-11-00234-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/eb2a28c9e8c8/nanomaterials-11-00234-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/5c83c38ca112/nanomaterials-11-00234-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cd5/7830501/de4d0e3c7e9f/nanomaterials-11-00234-g012.jpg

相似文献

1
Synthesis of Nanoparticles by Spark Discharge as a Facile and Versatile Technique of Preparing Highly Conductive Pt Nano-Ink for Printed Electronics.通过火花放电合成纳米颗粒作为一种制备用于印刷电子的高导电性铂纳米墨水的简便通用技术。
Nanomaterials (Basel). 2021 Jan 18;11(1):234. doi: 10.3390/nano11010234.
2
Optimizing Aerosol Jet Printing Process of Platinum Ink for High-Resolution Conductive Microstructures on Ceramic and Polymer Substrates.优化用于在陶瓷和聚合物基板上制备高分辨率导电微结构的铂油墨气溶胶喷射印刷工艺。
Polymers (Basel). 2021 Mar 16;13(6):918. doi: 10.3390/polym13060918.
3
Highly conductive electronics circuits from aerosol jet printed silver inks.由气溶胶喷射印刷银墨制成的高导电电子电路。
Sci Rep. 2021 Sep 13;11(1):18141. doi: 10.1038/s41598-021-97312-5.
4
Synthesis of monodisperse silver nanoparticles for ink-jet printed flexible electronics.用于喷墨打印柔性电子的单分散银纳米粒子的合成。
Nanotechnology. 2011 Oct 21;22(42):425601. doi: 10.1088/0957-4484/22/42/425601. Epub 2011 Sep 22.
5
Aerosol Jet Printing of Silver Lines with A High Aspect Ratio on A Heated Silicon Substrate.在加热的硅基板上气溶胶喷射印刷高纵横比银线。
Materials (Basel). 2020 Feb 5;13(3):730. doi: 10.3390/ma13030730.
6
Facile Preparation of Monodisperse Cu@Ag Core-Shell Nanoparticles for Conductive Ink in Printing Electronics.用于印刷电子学中导电油墨的单分散 Cu@Ag 核壳纳米粒子的简便制备方法。
Micromachines (Basel). 2023 Jun 27;14(7):1318. doi: 10.3390/mi14071318.
7
Nano oxide intermediate layer assisted room temperature sintering of ink-jet printed silver nanoparticles pattern.纳米氧化中间层辅助喷墨打印银纳米粒子图案的室温烧结。
Nanotechnology. 2019 Dec 6;30(49):495302. doi: 10.1088/1361-6528/ab40db. Epub 2019 Sep 3.
8
Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing.适用于喷墨打印的原位和快速合成导电图案的反应性导电油墨。
Molecules. 2019 Sep 30;24(19):3548. doi: 10.3390/molecules24193548.
9
Conductive films prepared from inks based on copper nanoparticles synthesized by transferred arc discharge.基于转移弧放电合成的铜纳米粒子的油墨制备的导电薄膜。
Nanotechnology. 2020 Jan 10;31(2):025302. doi: 10.1088/1361-6528/ab4524. Epub 2019 Sep 17.
10
Highly conductive copper nano/microparticles ink via flash light sintering for printed electronics.用于印刷电子的通过闪光灯烧结制备的高导电性铜纳米/微米颗粒油墨。
Nanotechnology. 2014 Jul 4;25(26):265601. doi: 10.1088/0957-4484/25/26/265601. Epub 2014 Jun 11.

引用本文的文献

1
Spark Discharge Synthesis and Characterization of Ge/Sn Janus Nanoparticles.Ge/Sn 双面纳米粒子的火花放电合成与表征
Nanomaterials (Basel). 2023 May 22;13(10):1701. doi: 10.3390/nano13101701.
2
Optimizing Aerosol Jet Printing Process of Platinum Ink for High-Resolution Conductive Microstructures on Ceramic and Polymer Substrates.优化用于在陶瓷和聚合物基板上制备高分辨率导电微结构的铂油墨气溶胶喷射印刷工艺。
Polymers (Basel). 2021 Mar 16;13(6):918. doi: 10.3390/polym13060918.

本文引用的文献

1
Fully inkjet-printed multilayered graphene-based flexible electrodes for repeatable electrochemical response.用于可重复电化学响应的全喷墨打印多层石墨烯基柔性电极。
RSC Adv. 2020 Oct 16;10(63):38205-38219. doi: 10.1039/d0ra04786d. eCollection 2020 Oct 15.
2
Aerosol-jet printing facilitates the rapid prototyping of microfluidic devices with versatile geometries and precise channel functionalization.气溶胶喷射打印有助于快速制造具有多种几何形状和精确通道功能化的微流控装置。
Appl Mater Today. 2020 Jun;19:100618. doi: 10.1016/j.apmt.2020.100618.
3
Graphene Flakes for Electronic Applications: DC Plasma Jet-Assisted Synthesis.
用于电子应用的石墨烯薄片：直流等离子体射流辅助合成
Nanomaterials (Basel). 2020 Oct 16;10(10):2050. doi: 10.3390/nano10102050.
4
A Review of Inkjet Printed Graphene and Carbon Nanotubes Based Gas Sensors.基于喷墨打印石墨烯和碳纳米管的气体传感器综述
Sensors (Basel). 2020 Oct 2;20(19):5642. doi: 10.3390/s20195642.
5
Design and fabrication of a smart sensor using in silico epitope mapping and electro-responsive imprinted polymer nanoparticles for determination of insulin levels in human plasma.利用计算机模拟表位作图和电响应印迹聚合物纳米颗粒设计与制备用于测定人血浆中胰岛素水平的智能传感器。
Biosens Bioelectron. 2020 Dec 1;169:112536. doi: 10.1016/j.bios.2020.112536. Epub 2020 Aug 28.
6
Improved electroless platinum contacts on CdZnTe X- and γ-rays detectors.CdZnTe X射线和γ射线探测器上改进的化学镀铂触点。
Sci Rep. 2020 Aug 13;10(1):13762. doi: 10.1038/s41598-020-70801-9.
7
Direct Patterned Zinc-Tin-Oxide for Solution-Processed Thin-Film Transistors and Complementary Inverter through Electrohydrodynamic Jet Printing.通过电流体动力喷射印刷制备用于溶液处理薄膜晶体管和互补逆变器的直接图案化锌锡氧化物。
Nanomaterials (Basel). 2020 Jul 3;10(7):1304. doi: 10.3390/nano10071304.
8
Silver nanoparticle conductive inks: synthesis, characterization, and fabrication of inkjet-printed flexible electrodes.银纳米颗粒导电油墨：喷墨打印柔性电极的合成、表征及制备
Sci Rep. 2020 Jun 1;10(1):8878. doi: 10.1038/s41598-020-65698-3.
9
Various Coating Methodologies of WO According to the Purpose for Electrochromic Devices.基于电致变色器件用途的氧化钨的各种镀膜方法
Nanomaterials (Basel). 2020 Apr 25;10(5):821. doi: 10.3390/nano10050821.
10
High-Temperature Gas Sensor Based on Novel Pt Single Atoms@SnO Nanorods@SiC Nanosheets Multi-heterojunctions.基于新型Pt单原子@SnO纳米棒@SiC纳米片多异质结的高温气体传感器
ACS Appl Mater Interfaces. 2020 May 13;12(19):21808-21817. doi: 10.1021/acsami.0c02160. Epub 2020 Apr 28.