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通过部分溶解的简单途径,从软木、硬木和农业秸秆纤维素中制备全纤维素复合材料。

Facile preparation of all-cellulose composites from softwood, hardwood, and agricultural straw cellulose by a simple route of partial dissolution.

机构信息

Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, Yunnan, China.

Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, Yunnan, China.

出版信息

Carbohydr Polym. 2021 Mar 15;256:117591. doi: 10.1016/j.carbpol.2020.117591. Epub 2021 Jan 4.

Abstract

In this study, we report a novel, facile, and green method that was used for creating a new all-cellulose composite (ACC) based on inorganic molten salt solvent. Three representatively native fibers from softwood (Pinus kesiya), hardwood (Eucalyptus globulus), and agricultural straw (Zea mays) were selected to verify the effect of the method. The welded sheets were thoroughly characterized and compared. Cellulose sheets from the pine exhibited excellent mechanical properties (σb 16.94 MPa) and thermal stability (T 265 °C) after the welding process, while the corn stalk sheets displayed more robust and thermostable features than the eucalyptus. The welding technique using inorganic metal salt hydrate provides a promising and convenient route to obtain firm sheet-materials with micro- or nano-structures from nature fibers.

摘要

在这项研究中,我们报告了一种新颖、简便、绿色的方法,用于使用无机熔融盐溶剂创建新型全纤维素复合材料(ACC)。我们选择了三种代表性的天然纤维,分别来自软木(松科)、硬木(桉属)和农业秸秆(玉米),以验证该方法的效果。对焊接片进行了全面的表征和比较。焊接后,来自松树的纤维素片表现出优异的机械性能(σb 16.94 MPa)和热稳定性(T 265°C),而玉米秸秆片则表现出比桉树更坚固和更耐热的特性。使用无机金属盐水合物的焊接技术为从天然纤维获得具有微观或纳米结构的坚固片状材料提供了一种有前途且方便的途径。

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