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用于热能存储的形状稳定相变材料/废旧轮胎复合材料的制备与表征

Preparation and characterization of form-stable phase change material/end-of-life tires composites for thermal energy storage.

作者信息

Konuklu Yeliz

机构信息

Nanotechnology Application and Research Centre, Niğde Ömer Halisdemir University Turkey.

Department of Chemistry, Niğde Ömer Halisdemir University Turkey.

出版信息

Turk J Chem. 2020 Apr 1;44(2):421-434. doi: 10.3906/kim-1911-23. eCollection 2020.

Abstract

The management of end-of-life tires (ELT) waste gains importance in aspect of possible environmental and economic issues so the waste recycling becomes unavoidable. This study describes the fabrication and characterization of a new phase changing material (PCM)/ELT microcomposites that could be used in thermal energy storage. Paraffin together with the 4 fatty acids and ELT rubber powder are used as PCMs and as the supporting material, respectively. Paraffin/ELT composites are fabricated, as well, by the vacuum impregnation method in order to investigate the effect of the preparation method. The thermal, morphological, and chemical properties of the prepared PCM/ELT rubber microcomposites are determined with differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and FTIR, respectively. Additionally, the effects of the PCM amount on the composite materials are investigated. As a result of DSC results, the melting temperature and latent heat of the paraffin/ELT rubber microcomposites are determined as 37.2 °C and 80.79 J/g for direct impregnation method and 36.8 °C and 80.69 J/g for vacuum impregnation method, respectively. Based on the findings of this study, it can be claimed that PCM/ELT rubber microcomposites can be used as energy-saving materials in thermal energy storage applications.

摘要

废旧轮胎(ELT)废弃物的管理在可能的环境和经济问题方面变得愈发重要,因此废弃物回收变得不可避免。本研究描述了一种可用于热能存储的新型相变材料(PCM)/ELT微复合材料的制备与表征。石蜡与4种脂肪酸以及ELT橡胶粉分别用作相变材料和支撑材料。还通过真空浸渍法制备了石蜡/ELT复合材料,以研究制备方法的影响。分别用差示扫描量热法(DSC)、扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)测定了所制备的PCM/ELT橡胶微复合材料的热性能、形态和化学性质。此外,还研究了相变材料用量对复合材料的影响。根据DSC结果,直接浸渍法制备的石蜡/ELT橡胶微复合材料的熔点和潜热分别为37.2℃和80.79J/g,真空浸渍法制备的分别为36.8℃和80.69J/g。基于本研究的结果,可以认为PCM/ELT橡胶微复合材料可作为热能存储应用中的节能材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b6b/7671213/42c53cc21fe1/turkjchem-44-421-fig001.jpg

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